I collected 3D velocity data in a river. the recorded timeseries of velocity components $(u,v,w)$ contains turbulent and mean part. Reynolds Shear Stress can be estimated from
$$u=u'+U$$
$$\langle u'w' \rangle=\text{cov}( u'_{t}, w'_{t} )$$
and to extract velocity fluctuation
$$\langle u' \rangle=\sqrt{\text{var}( u'_{t})}$$
$$\langle w' \rangle=\sqrt{\text{var}( w'_{t})}$$
where $\langle\rangle$ shows the averaging over the time span of $t$.
My question is why $\langle u' \rangle\langle w' \rangle$ is not equal to $\langle u' w' \rangle$
Example:
$\langle u'w' \rangle=$ {55.0336, 24.3896, 22.4693, 21.9123, 31.9418, 34.791, 30.9995, -1.12979, -2.76629, -5.60678, -7.23715, -11.1097, -24.4944, -31.5994, -49.414, -92.9571, -97.5096, -91.7745, -141.235, -110.685}
$\langle u' \rangle^2=$ {691.168, 438.195, 402.749, 332.111, 470.982, 565.431, 454.04, 192.986, 94.7298, 110.964, 81.9545, 128.034, 198.726, 297.308, 508.916, 910.229, 922.968, 983.665, 1311.84, 1011.1}
$\langle w' \rangle^2=${46.2054, 28.1408, 43.3248, 32.9785, 32.092, 40.1115, 28.038, 13.3292, 6.74369, 7.3284, 6.98387, 11.5178, 18.7025, 29.0199, 39.9626, 60.4201, 74.1318, 80.8566, 89.0198, 78.8576}