Let $\mathbf{T}$ be total scatter matrix of the data (i.e. covariance matrix but without normalizing by the number of data points), $\mathbf{W}$ be the within-class scatter matrix, and $\mathbf{B}$ be between-class scatter matrix. See here for definitionsSee here for definitions. Conveniently, $\mathbf{T}=\mathbf{W}+\mathbf{B}$.
LDA performs eigen-decomposition of $\mathbf{W}^{-1} \mathbf{B}$, takes its non-orthogonal (!) unit eigenvectors as discriminant axes, and projections on the eigenvectors as discriminant components (a made-up term). For each discriminant component, we can compute a ratio of between-class variance $B$ and within-class variance $W$, i.e. signal-to-noise ratio $B/W$. It turns out that it will be given by the corresponding eigenvalue of $\mathbf{W}^{-1} \mathbf{B}$ (Lemma 1, see below). All eigenvalues of $\mathbf{W}^{-1} \mathbf{B}$ are positive (Lemma 2) so sum up to a positive number $\mathrm{tr}(\mathbf{W}^{-1} \mathbf{B})$ which one can call total signal-to-noise ratio. Each discriminant component has a certain proportion of it, and that is, I believe, what "proportion of trace" refers to. See this answer by @ttnphns for a similar discussionSee this answer by @ttnphns for a similar discussion.
However, I am reluctant to refer to these component variances as "explained variances" (let's call them "captured variances" instead). For each LDA component, one can compute the amount of variance it can explain in the data by regressing the data onto this component; this value will in general be larger than this component's own "captured" variance. If there is enough components, then together their explained variance must be 100%. See my answer here for how to compute such explained variance in a general case: Principal component analysis "backwards": how much variance of the data is explained by a given linear combination of the variables?Principal component analysis "backwards": how much variance of the data is explained by a given linear combination of the variables?