If you think geometrically...

In the $X$-$Y$ plane, curves of constant $Z = Y/X$ are lines through the origin. ($Y/X$ is the slope.) One can read off the value of $Z$ from a line through the origin by finding its intersection with the line $X=1$. (If you've ever studied projective space: here $X$ is the homogenizing variable, so looking at values one the slice $X=1$ is a relatively natural thing to do.)

Consider a small interval of $Z$s, $(a,b)$. This interval can also be discussed on the line $X+1$ as the line segment from $(1,a)$ to $(1,b)$. The set of lines through the origin passing through this interval forms a solid triangle in the square $(X,Y) \in U = [0,1]\times[0,1]$, which is the region we're actually interested in. If $0 \leq a < b \leq 1$, then the area of the triangle is $\frac{1}{2}(1-0)(b-a)$, so keeping the length of the interval constant and sliding it up and down the line $X=1$ (but not past $0$ or $1$), the area is the same, so the probability of picking an $(X,Y)$ in the triangle is constant, so the probability of picking a $Z$ in the interval is constant.

However, for $b>1$, the boundary of the region $U$ turns away from the line $X = 1$ and the triangle is truncated. If $1 \leq a < b$, the projections down lines through the origin from $(1,a)$ and $(1,b)$ to the upper boundary of $U$ are to the points $(1/a,1)$ and $(1/b,1)$. The resulting area of the triangle is $\frac{1}{2}(\frac{1}{a} - \frac{1}{b})(1-0)$. From this we see the area is not uniform and as we slide $(a,b)$ further and further to the right, the probability of selecting a point in the triangle decreases to zero.

Then the same algebra demonstrated in other answers finishes the problem. In particular, returning to the OP's last question, $f_Z(1/2)$ corresponds to a line that reaches $X=1$, but $f_Z(2)$ does not, so the desired symmetry does not hold.

If you think geometrically...

In the $X$-$Y$ plane, curves of constant $Z = Y/X$ are lines through the origin. ($Y/X$ is the slope.) One can read off the value of $Z$ from a line through the origin by finding its intersection with the line $X=1$. (If you've ever studied projective space: here $X$ is the homogenizing variable, so looking at values on the slice $X=1$ is a relatively natural thing to do.)

Consider a small interval of $Z$s, $(a,b)$. This interval can also be discussed on the line $X=1$ as the line segment from $(1,a)$ to $(1,b)$. The set of lines through the origin passing through this interval forms a solid triangle in the square $(X,Y) \in U = [0,1]\times[0,1]$, which is the region we're actually interested in. If $0 \leq a < b \leq 1$, then the area of the triangle is $\frac{1}{2}(1-0)(b-a)$, so keeping the length of the interval constant and sliding it up and down the line $X=1$ (but not past $0$ or $1$), the area is the same, so the probability of picking an $(X,Y)$ in the triangle is constant, so the probability of picking a $Z$ in the interval is constant.

However, for $b>1$, the boundary of the region $U$ turns away from the line $X = 1$ and the triangle is truncated. If $1 \leq a < b$, the projections down lines through the origin from $(1,a)$ and $(1,b)$ to the upper boundary of $U$ are to the points $(1/a,1)$ and $(1/b,1)$. The resulting area of the triangle is $\frac{1}{2}(\frac{1}{a} - \frac{1}{b})(1-0)$. From this we see the area is not uniform and as we slide $(a,b)$ further and further to the right, the probability of selecting a point in the triangle decreases to zero.

Then the same algebra demonstrated in other answers finishes the problem. In particular, returning to the OP's last question, $f_Z(1/2)$ corresponds to a line that reaches $X=1$, but $f_Z(2)$ does not, so the desired symmetry does not hold.