As a first step I would ask myself whether the series looks mean-reverting. Since the series has a specific "inverted U" shape, it does not seem to be mean-reverting. Therefore I suggest it is not stationary.
However there is chance that your series could be trend-stationary. If you are able to find any function f(t) of time t that describes the trend of "inverted U", you can remove the trend and what remains could (maybe) be stationary.
One shape of such deterministic function f(t) is a linear trend that you have written in your first formula. However this is not an option for you, because clearly the trend is not linear but "inverted U" shape.
You could try to capture the deterministic trend by another f(t) function, for example a quadratic form (instead of linear) or, but the assumption of a form based on dummy time variablesquadratic trend in the generating process appears "too artificial" to me (i.e. there is no rational expectation for the variable "intensity" to be a quadratic time process)
If you are able to find such f(t) that you can fit into your regression formula and you will obtain stationary residuals, then it is a win for you, because you can apply such model. (although I have also seen doubts about this approach on a theoretical level)
If you are not able to find such f(t) that would lead to stationary residuals in your regression formula, then the time series is indeed non stationary. In that case you must apply differencing (of order 1 or possibly 2) on your time series.
YourHowever, your series is pretty short (few observations). To build a robust model, you would do better to connect all days together into one series. Such series will have strong seasonality (morning/evening/noon) and you would be able to employ some seasonal time series model. Because indeed the "inverted U" shape appears to be a seasonal pattern and nothing else.