By definition, the law of $X_n - \lfloor X_n\rfloor$ is
$$F_n(x) = \Pr(X_n - \lfloor X_n\rfloor \le x)$$
for $0 \le x \lt 1$. The event $E^{(n)}: X_n - \lfloor X_n\rfloor \le x$ is a countable union of the disjoint events $E^{(n)}_i: i \le X_n \le i + x$ for $i=0, 1, 2, \ldots$. Therefore (because probability is countably summable)
$$F_n(x) = \Pr(E^{(n)})= \sum_{i=0}^\infty \Pr(E^{(n)}_i).$$
When $X_n$ has an Exponential$(\lambda/n)$ distribution,
$$\Pr(E^{(n)}_i) = \Pr( i \le X_n \le i + x) = e^{-\lambda i/n} - e^{-\lambda (i+x)/n} = \left(1 - e^{-\lambda x / n}\right)e^{-\lambda i/n},$$
producing
$$F_n(x) = \left(1 - e^{-\lambda x / n}\right)\sum_{i=0}^\infty e^{-\lambda i/n}.$$
The last term sums a geometric series with initial term $1$ and common ratio $e^{-\lambda/n}$, immediately simplifying the whole expression to
$$F_n(x) = \frac{1 - e^{-\lambda x/n}}{1 - e^{-\lambda/n}}.$$
The limiting value as $n\to \infty$ is most easily obtained with L'Hopital's Rule,
$$\lim_{n\to\infty} F_n(x) = \lim_{n\to\infty} \frac{\lambda x e^{-\lambda x/n}}{\lambda e^{-\lambda/n}} = x\lim_{n\to\infty} e^{\lambda/n(1-x)} = x.$$
This is the law of the Uniform distribution on $[0, 1)$.