Suppose we already know sum of $U(0,1)$ has a Irwin-Hall distribution.
Now your question changes to find the pdf (or CDF) of $\frac{X}{Y}$ when X had a $U(0,1)$ distribution and $Y$ has a Irwin-Hall distribution.
First we need to find he joint pdf of $X$ and $Y$.
Let $Y_1=X_1\\Y_2=X_1+X_2\\Y_3=X_1+X_2+X_3$
Then
$X_1=Y_1\\X_2=Y_2-Y_1\\X_3=Y_3-Y_2-Y_1$
$\therefore$
$J=\begin{vmatrix}
\frac{\partial X_1}{\partial Y_1} & \frac{\partial X_1}{\partial Y_2} &\frac{\partial X_1}{\partial Y_3} \\
\frac{\partial X_2}{\partial Y_1} & \frac{\partial X_2}{\partial Y_2} &\frac{\partial X_2}{\partial Y_3} \\
\frac{\partial X_3}{\partial Y_1} & \frac{\partial X_3}{\partial Y_2} &\frac{\partial X_3}{\partial Y_3}
\end{vmatrix}=-1$
Since $X_1, X_2, X_3$ are i.i.d with $U(0,1),$ therefore, $f(x_1,x_2,x_3)=f(x_1)f(x_2)f(x_3)=1$
The joint distribution with $y_1,y_2,y_3$ is
$g(y_1,y_2,y_3)=f(y_1,y_2,y_3)|J|=1$
Next let us integrate out the $Y_2$ and we can get the joint distribution of $Y_1$ and $Y_3$ i.e the joint distribution of $X_1$ and $X_1+X_2+X_3$
As suggested by whuber now I changed the the limits
$$h(y_1,y_3)=\int_{y_1+1}^{y_3-1} g(y_1,y_2,y_3)dy_2=\int_{y_1+1}^{y_3-1} 1 dy_2=y_3-y_1-2 \tag{1}$$
Now, we know the joint pdf of $X,Y$ i.e joint pdf $X_1$ and $X_1+X_2+X_3$ is $y_3-y_1-2$.
Next let find the pdf of $\frac{X}{Y}$
We need another transformation:
Let $Y_1=X\\Y_2=\frac{X}{Y}$
Then $X=Y_1\\Y=\frac{Y_1}{Y_2}$
Then
$J=\begin{vmatrix}
\frac{\partial x}{\partial y_1} & \frac{\partial x}{\partial y_2}\\
\frac{\partial y}{\partial y_1} & \frac{\partial y}{\partial y_2}
\end{vmatrix}=
\begin{vmatrix}
1 & 0\\
\frac{1}{y_2} & -\frac{y_1}{y_2^2}
\end{vmatrix}=-\frac{y_1}{y_2^2}$
we already the joint distribution of $X,Y$ from above steps ref (1).
$\therefore$
$g_2(y_1,y_2)=h(y_1,y_3)|J|=(y_3-y_1-2)\frac{y_1}{y_2^2}$
Next, we integrate the $y_1$ out we get the pdf of $y_2$ then we get the pdf of $\frac{X}{Y}$
$$h_2(y_2)=\int_0^1(y_3-y_1-2)\frac{y_1}{y_2^2}dy_1=\frac{1}{y_2^2}(\frac{y_3}{2}-\frac{1}{3}-1)\tag{2}$$
This is the pdf of $X/Y$ i.e $\frac{X_1}{X1+X_2+X_3}$
We are not finish yet, what is $y_3$ in (2) then?
We know that $Y_3=X_1+X_2+X_3$ from the first transformation.
So at least we know $Y_3$ has a Irwin-Hall distribution.
I wonder can we plug the Irwin-Hall for $n=3$ pdf to (2) to get a explicit formula? or can we do some simulations from here as Glen suggested?