I was pondering how to formulate the simplest possible elementary solution to this problem and it occurred to me we can avoid any consideration of Beta functions (no Stirling's approximation needed; indeed, even information about the moments of Beta distributions is unnecessary). The result is extremely general and, I hope, interesting.
Here, for the record, is what I will show:
Let $f$ be a positive multiple of any probability density function that is
bounded, unimodal, and twice differentiable in a neighborhood of
its mode. Let the second derivative at the mode equal $-a$. Then any sequence
of random variables $X_n$ with distribution functions proportional to
$$t\to f^n\left(\frac{t}{\sqrt{an}}\right)$$ converges in distribution to the
Standard Normal distribution.
Notation, assumptions, and preliminary simplifications
Permit me to use $n+1$ rather than $n$ as the index, so that $$f_n(t)\ \propto\ t^n(1-t)^n = (t(1-t))^n = f(t)^n$$ (for $0\le t\le 1$), thereby avoiding writing "$n-1$" too often. In the question $f(t) = t(1-t)$ for $0\le t \le 1$ (and otherwise equals zero). However, this formula is a distracting, irrelevant detail.
Here's all we need to assume about $f:$
- There is a constant $c$ for which $cf$ is a probability density function. This means it is defined almost everywhere on all real numbers, integrable, with unit integral. Obviously $c^{-1}=\int f(t)\,\mathrm{d}t.$
- $f$ is bounded and unimodal. That is, $f$ has a unique finite maximum value.
- $f$ has a second derivative in a neighborhood of its mode.
These are clearly true of the $f$ in the question.
Letting $\mu$ be the mode, we may with no loss of generality analyze the function $t\to f(t-\mu),$ which has all the properties assumed of $f$ and whose mode is $0.$
Writing
$$f(t) = 1 - \frac{a}{2}\left(1 + g(t)\right)t^2,$$
the third assumption implies
$$\lim_{t\to 0} g(t) = 0$$
and there is some positive number $\epsilon$ for which whenever $|t|\le \epsilon,$ $g(t) \ge 0.$ Moreover, since $0$ is the unique mode, $a$ must be positive.
Without any loss of generality, replace $f$ by the function $t\to f(t)/f(0),$ making the largest value of $f$ exactly $1,$ attained at its mode $0.$
We are going to consider a sequence of probability density functions determined by powers of $f.$ First we need to normalize those powers, so let
$$c_n^{-1} = \int f^n (t)\,\mathrm{d}t.$$
This is always possible because
$$\int f^n(t)\,\mathrm{d}t \le \sup(f)\int f^{n-1}(t)\,\mathrm{d}t\ = \int f^{n-1}(t)\,\mathrm{d}t$$
shows recursively that the integrals of $f^n$ cannot increase and therefore are bounded.
A final preliminary manipulation is to standardize $f^n:$ we are going to analyze the sequence
$$f_n(t) = f\left(\frac{t}{\sqrt{an}}\right)^n.$$
The next few steps will show why this is effective at producing just the right cancellation of factors in the calculation. First, though, let's look at an example.
As $n$ grows, $f$ spreads out from its mode, pushing all "satellites" out and dampening them, leaving a graph that rapidly approaches a multiple of a Normal pdf. (The plot of $f$ in the upper left corner has not yet been rescaled to a height of $1$ at its mode. The next plot of $f_1$ has been so scaled and is plotted on an $x$ axis expanded by a factor of $\sqrt{a}$ to show detail.)
Analysis
Let $t$ be any real number. Once $n$ exceeds $N(t)=t^2 / (a\epsilon^2),$ $|t|/\sqrt{an}\le \epsilon$ puts this value into the neighborhood where $f$ behaves nicely. From now on take $n\gt N(t).$
We are going to estimate the value of $f^n(t)$ by using logarithms. This is the crux of the matter and it is where all the algebra is done. Fortunately, it's easy:
$$\begin{aligned}
\log\left(f^n(t)\right) &= n \log(f(t)) \\
&= n \log f\left(\frac{t}{\sqrt{an}}\right) \\
&= n \log \left(1 - \frac{a}{2}\left(\frac{t}{\sqrt{an}}\right)^2\left(1 + g\left(\frac{t}{\sqrt{an}}\right) \right) \right) \\
&= n\log\left(1 - \frac{t^2}{2n}\left(1 + g\left(\frac{t}{\sqrt{an}}\right)\right)\right)
\end{aligned}$$
Because $g$ shrinks to $0$ for small arguments, a sufficiently large value of $n$ assures that the argument of the logarithm in that last expression is of the form $1-u$ for an arbitrarily small value of $u.$ This permits us to approximate the logarithm using Taylor's Theorem (with remainder), giving
$$\begin{aligned}
n\log\left(f^n(t)\right) &= -\frac{t^2}{2}\left(1 + g\left(\frac{t}{\sqrt{an}}\right)\right) + \frac{R}{n}\, \tilde{t}^4 \left(1 + g\left(\frac{\tilde t}{\sqrt{an}}\right)\right)^2
\end{aligned}$$
where $0\le |\tilde{t}| \le |t|$ and $R$ is some number (related to the remainder term in the Taylor expansion). Taking the limit as $n\to\infty$ makes the remainder and all the $g()$ terms disappear, leaving
$$\lim_{n\to\infty} \log\left(f(t)^n\right) = -\frac{t^2}{2},$$
whence
$$\lim_{n\to\infty} f(t)^n = \exp\left(-\frac{t^2}{2}\right).$$
It follows (requiring only an intuitive, elementary proof) that the sequence of normalizing constants $c_n$ must approach the normalizing constant for the right hand side--which exists and, as is well known, equals $\sqrt{2\pi}.$ Consequently
$$\lim_{n\to\infty} f_n(t) = \frac{1}{\sqrt{2\pi}} \exp\left(-\frac{t^2}{2}\right),$$
which is the standard Normal density $\phi.$
Conclusions
When $X_n$ is a sequence of random variables having densities $f_n,$ for every number $t$ the limit of their densities is $\phi(t).$ It follows easily that the limit of their distribution functions is $\Phi,$ the standard Normal distribution.
In the case of the Beta$(n,n)$ distributions, $f(t)=t(1-t)$ has a unique mode at $\mu=1/2,$ where it can be expressed (up to a constant multiple) as
$$4f(t) = 1 - \frac{8}{2}(t-1/2)^2.$$
From this we can read off the value $a=8.$ Following our preliminary simplifications, this says the distribution of $\sqrt{an}(X_n - \mu) = \sqrt{8n}(X_n-\mu)$ converges to the standard Normal distribution. Because asymptotically the ratio of $\sqrt{8n}$ and $2\sqrt{2n+1}$ becomes unity, the statement in the original question is proven.