Using wikipedia I found a way to calculate the probability mass function resulting from the sum of two Poisson random variables. However, I think that the approach I have is wrong.
Let $X_1, X_2$ be two independent Poisson random variables with mean $\lambda_1, \lambda_2$, and $S_2 = a_1 X_1+a_2 X_2$, where the $a_1$ and $a_2$ are constants, then the probability-generating function of $S_2$ is given by $$ G_{S_2}(z) = \operatorname{E}(z^{S_2})= \operatorname{E}(z^{a_1 X_1+a_2 X_2}) G_{X_1}(z^{a_1})G_{X_2}(z^{a_2}). $$ Now, using the fact that the probability-generating function for a Poisson random variable is $G_{X_i}(z) = \textrm{e}^{\lambda_i(z - 1)}$, we can write the probability-generating function of the sum of the two independent Poisson random variables as $$ \begin{aligned} G_{S_2}(z) &= \textrm{e}^{\lambda_1(z^{a_1} - 1)}\textrm{e}^{\lambda_2(z^{a_2} - 1)} \\ &= \textrm{e}^{\lambda_1(z^{a_1} - 1)+\lambda_2(z^{a_2} - 1)}. \end{aligned} $$ It seems that the probability mass function of $S_2$ is recovered by taking derivatives of $G_{S_2}(z)$ $\operatorname{Pr}(S_2 = k) = \frac{G_{S_2}^{(k)}(0)}{k!}$, where $G_{S_2}^{(k)} = \frac{d^k G_{S_2}(z)}{ d z^k}$.
Is this is correct? I have the feeling I cannot just take the derivative to obtain the probability mass function, because of the constants $a_1$ and $a_2$. Is this right? Is there an alternative approach?
If this is correct can I now obtain an approximation of the cumulative distribution by truncating the infinite sum over all k?