Since $\mathbf{A} = (A_1,...,A_n) \sim \text{IID } p$, it follows that we have the marginal distributions:
$$n \cdot q_\mathbf{A}(a) = \sum_{i=1}^n \mathbb{I}(A_i = a) \sim \text{Bin}(n, p(a))
\quad \quad \quad \text{for all } a \in \mathcal{A}.$$
Hence, we can write the expectation as:
$$\begin{equation} \begin{aligned}
\phi_n
&= \mathbb{E} \Big[ \|p-q_\mathbf{A}\|_1 \Big] \\[6pt]
&= \mathbb{E} \Bigg[ \sum_{a \in \mathcal{A}} |p(a) - q_\mathbf{A}(a)| \Bigg] \\[6pt]
&= \sum_{a \in \mathcal{A}} \mathbb{E} \Bigg[ |p(a) - q_\mathbf{A}(a)| \Bigg] \\[10pt]
&= \sum_{a \in \mathcal{A}} \sum_{r=0}^n |p(a) - r/n| \cdot \text{Bin}(r|n,p(a)) \\[10pt]
&= \sum_{a \in \mathcal{A}} \sum_{r=0}^n |p(a) - r/n| \cdot {n \choose r} p(a)^r (1-p(a))^{n-r}. \\[6pt]
\end{aligned} \end{equation}$$
The lower bound for this expectation is $\phi_n=0$. For any mass function $p$ that is a point-mass on a single elements of $\mathcal{A}$, we have $\|p-q_\mathbf{A}\|_1=0$ almost surely, which gives this lower bound.
The upper bound can be formed by taking the uniform distribution over the support. If $p(a) = 1/|\mathcal{A}|$ for all $a \in \mathcal{A}$ then we have:
$$\begin{equation} \begin{aligned}
\phi_n
&= \sum_{a \in \mathcal{A}} \sum_{r=0}^n |p(a) - r/n| \cdot {n \choose r} p(a)^r (1-p(a))^{n-r} \\[6pt]
&\leqslant \sum_{a \in \mathcal{A}} \sum_{r=0}^n \Bigg| \frac{1}{|\mathcal{A}|} - \frac{r}{n} \Bigg| \cdot {n \choose r} \frac{1}{|\mathcal{A}|^n} \\[6pt]
&= \frac{1}{|\mathcal{A}|^n} \sum_{a \in \mathcal{A}} \sum_{r=0}^n {n \choose r} \Bigg| \frac{1}{|\mathcal{A}|} - \frac{r}{n} \Bigg| \\[6pt]
&= \frac{1}{n} \cdot \frac{1}{|\mathcal{A}|^{n-1}} \sum_{r=0}^n {n \choose r} \Bigg| \frac{n}{|\mathcal{A}|} - r \Bigg|. \\[6pt]
\end{aligned} \end{equation}$$
This gives a relatively tight upper bound. A weaker upper bound can be obtained by applying Jensen's inequality, giving:
$$\begin{equation} \begin{aligned}
\phi_n
&= \sum_{a \in \mathcal{A}} \mathbb{E} \Bigg[ |p(a) - q_\mathbf{A}(a)| \Bigg] \\[6pt]
&\leqslant \Bigg( \sum_{a \in \mathcal{A}} \mathbb{E} \Bigg[ (p(a) - q_\mathbf{A}(a))^2 \Bigg] \Bigg)^{1/2} \\[6pt]
&= \frac{1}{n} \Bigg( \sum_{a \in \mathcal{A}} \mathbb{E} \Bigg[ (n \cdot q_\mathbf{A}(a) - n \cdot p(a))^2 \Bigg] \Bigg)^{1/2} \\[6pt]
&= \frac{1}{n} \Bigg( \sum_{a \in \mathcal{A}} \mathbb{V} [ n \cdot q_\mathbf{A}(a) ] \Bigg)^{1/2} \\[6pt]
&= \frac{1}{\sqrt{n}} \Bigg( \sum_{a \in \mathcal{A}} p(a) (1-p(a)) \Bigg)^{1/2} \\[6pt]
&\leqslant \frac{1}{\sqrt{n}} \Bigg( 1-\frac{1}{|\mathcal{A}|} \Bigg)^{1/2} \\[6pt]
&\leqslant \sqrt{\frac{1 - 1/ |\mathcal{A}|}{n}}. \\[6pt]
\end{aligned} \end{equation}$$