The question as phrased is unclear (especially what exactly is meant by "when central limit theorem is applied"? Does it mean "when the conditions for the CLT hold?" for example -- and if so, which CLT?), and you provide no reasoning for us to discuss, so I'll mostly confine myself to some general comments.
Lamentably the question seems to perpetuate all manner of misunderstandings, common in a host of texts (and sets of notes) of mostly very poor quality. It's little wonder misconceptions abound.
Firstly, the "distribution of the sample" is not at issue (that's discrete, for starters), its what is the population distribution that the sample was drawn from that's the concern. This means 1. and 3. as phrased don't really make sense. (5 skirts around saying the 'distribution of the sample' phrasing just enough for me to give it the benefit of the doubt.)
Let's also take - for simplicity of discussion - that the $X_i$ are assumed "independent, identically distributed". There are versions of the CLT that don't require those, but some of the options hint that it's a more classical CLT we're dealing with.
If we interpret them instead to be meaning to ask about the distribution from which the sample was drawn and the population distribution of sums of size $n$, then those options make more sense as statements to consider.
Even with that change, 1. is still obviously false. The population distribution doesn't change when you take a bigger sample from it.
Statement 2. isn't in any sense a consequence of CLT (indeed as stated, for a constant variance of the components, it's true whenever the random variables in the mean are not perfectly dependent). The classical CLT itself uses the fact (i.e. it relies on it) that with iid $X_i$, $\text{Var}(\bar{X})=\sigma/\sqrt{n}$. This follows from basic properties of variance.
While statement 5. is actually true under appropriate conditions, the CLT doesn't actually doesn't quite say that (to really say something like that you need something more than the CLT). It's important to know what the CLT does say -- at least a classic version. The Wikipedia page on the CLT isn't too bad; start with the statement of the Lindeberg–Lévy CLT; what it says is under certain conditions that
$\sqrt{n}\bigg(\bigg(\frac{1}{n}\sum_{i=1}^n X_i\bigg) - \mu\bigg)\ \xrightarrow{d}\ N(0,\;\sigma^2)$
(Statement 4. is very often true as well, but there's some additional subtleties with it.)
When the population follows normal distribution N[u,sigma^2], sample mean and sample variance are independent. How do I prove this true or wrong?
Well, there are a number of approaches. For example it follows from Cochran's theorem, or Basu's theorem.
However, this is quite a different sort of question and really deserves a question of its own.