The missing entries are not uniquely determined, unless additional information is known.
The only requirements on the missing entries are that they be symmetric, i.e., A(2,3) = A(3,2), A(2,4) = A(4,2), A(3,4) = A(4,3), and that A be positive semi-definite.
I used CVX to maximize the sum of the unknown entries, then separately ran it to minimize the sum of the unknown entries, then separately ran it to minimize the sum of absolute values of the unknown entries. This produces three different solutions, among an infinite number of possibilities.
Maximum sum:
A =
1.0000 0.5000 0.6000 0.7000
0.5000 1.0000 0.9928 0.9685
0.6000 0.9928 1.0000 0.9913
0.7000 0.9685 0.9913 1.0000
Minimum sum:
A =
1.0000 0.5000 0.6000 0.7000
0.5000 1.0000 -0.1400 0.0400
0.6000 -0.1400 1.0000 0.2200
0.7000 0.0400 0.2200 1.0000
Minimum sum of absolute value:
A=
1.0000 0.5000 0.6000 0.7000
0.5000 1.0000 0.0000 0.0000
0.6000 0.0000 1.0000 0.1354
0.7000 0.0000 0.1354 1.0000