As an alternative approach to Marc's:
A symmetric function $k : \mathcal X \times \mathcal X \to \mathbb R$ is a kernel function iff there is some "feature map" $\varphi : \mathcal X \to \mathcal H$ such that $k(x, y) = \langle \varphi(x), \varphi(y) \rangle_{\mathcal H}$, where $\mathcal H$ is a Hilbert space.
Let $\varphi_i$ be the feature map for $k_i$, and $\mathcal H_i$ its Hilbert space.
Now, $\mathcal H_p := \mathcal H_1 \oplus \mathcal H_2$ is a Hilbert space, and $\varphi_p := \sqrt{a_1} \varphi_1 \oplus \sqrt{a_2} \varphi_2$ is a feature map from $\mathcal X$ to it as long as $a_1, a_2 \ge 0$. (For finite-dimensional feature spaces, this is just concatenating the feature maps together.) Note that
\begin{align}
\langle \varphi_p(x), \varphi_p(y) \rangle_{\mathcal H_p}
&= \langle \sqrt{a_1} \varphi_1(x) \oplus \sqrt{a_2} \varphi_2(x), \sqrt{a_1} \varphi_1(y) \oplus \sqrt{a_2} \varphi_2(x) \rangle_{\mathcal H_1 \oplus \mathcal H_2}
\\&= a_1 \langle \varphi_1(x), \varphi_1(y) \rangle_{\mathcal H_1} + a_2 \langle \varphi_2(x), \varphi_2(y) \rangle_{\mathcal H_2}
\\&= k_p(x, y)
,\end{align}
so $k_p$ has feature map $\varphi_p$, and is therefore a valid kernel.
To your "in general" question at the end: if you want to prove them for arbitrary kernels, the two main techniques are the one Marc used and the one I used. Often, though, for Marc's approach we directly use the Mercer condition rather than the integral form, which can be easier to reason about:
A symmetric function $k : \mathcal X \times \mathcal X \to \mathcal R$ is positive semidefinite if and only if for all $M$, all $x_1, \dots, x_M \in \mathcal X$, and all $c_1, \dots, c_M \in \mathbb R$, $\sum_{i=1}^M \sum_{j=1}^M c_i k(x_i, x_j) c_j \ge 0$.
We can also use the following equivalent form:
A symmetric function $k : \mathcal X \times \mathcal X \to \mathcal R$ is positive semidefinite if and only if for all $M$, all $x_1, \dots, x_M \in \mathcal X$, the matrix $K$ with $K_{ij} = k(x_i, x_j)$ is positive semidefinite.
I previously gave brief proofs for several such properties in this answer.