The trick to finding moments, when the distribution is summarized, is to think in terms of totals rather than averages.
Here, we are given five proportions $p_0, p_1, p_2, p_3, p_4$ for the grade distribution. There were an unknown number $N$ of grades, whence $p_0N$ were $0$, ..., and $p_4N$ were $4$. Therefore the total grade was
$$p_0N \times 0 + p_1N \times 1 + \ldots + p_4N \times 4 = (p_1 + 2p_2 + 3p_3 + 4p_4)N.$$
The mean grade by definition is the total divided by the number:
$$m = \mbox{Mean} = (p_1 + 2p_2 + 3p_3 + 4p_4)N/N = p_1 + 2p_2 + 3p_3 + 4p_4.$$
To obtain the variance, consider that $p_0N$ of the grades were $0$ and, by definition, each contributes $(0-m)^2$ to the total sum of squared deviations from the mean. The grades of $1$ contribute $(1-m)^2$, etc. Therefore the total sum of squared deviations equals
$$p_0N \times (0-m)^2 + p_1N \times (1-m)^2 + \ldots + p_4N \times (4-m)^2.$$
We don't know $N$, so it's senseless to divide this by $N-1$, as is sometimes done for variance estimators, but we can divide by $N$ to obtain the variance of the grades as
$$\mbox{Variance} = p_0 m^2 + p_1 (1-m)^2 + p_2 (2-m)^2 + p_3 (3-m)^2 + p_4 (4-m)^2.$$
The standard deviation is the square root of this quantity.
Higher moments and their relatives, such as skewness and kurtosis, are obtained with similar calculations. They are amenable to spreadsheet formulas.
Incidentally (to explain some of the comments), these results are biased when the values represent binned counts of more fine-grained values. The variance formula, for instance, does not account for variation within each bin. There are standard ways to correct the formulas (such as Shepard's Corrections). These tend to require strong assumptions (such as near-normality of the underlying distribution along with some technical requirements on the bins: you need the distribution to be tapering off within the terminal bins), so they are rarely used (as far as I know). One can also fit a continuous distribution to the data (in various ways) and then estimate the moments from the moments of the fit.