Well,
$$ {\rm cov}(Y_{ij}, Y_{ik})
= {\rm cov}(u_{i} + e_{ij}, u_{i} + e_{ik})
$$
since the constant term, $\mu$, does not affect variances or covariances. By the bilinearity of covariance we have
$$ {\rm cov}(Y_{ij}, Y_{ik})
=
{\rm cov}(u_{i}, u_{i})
+ {\rm cov}(u_{i}, e_{ik})
+ {\rm cov}(e_{ij}, u_{i})
+ {\rm cov}(e_{ij}, e_{ik})
$$
By independence of $u_{i}$ and each $e_{ij}, e_{ik}$ and independence between $e_{ij}$ and $e_{ik}$ (which must be assumed for this model to make sense), the 2nd, 3rd and 4th terms are all zero above (since independence between two variables implies that their covariance is 0). So,
$$ {\rm cov}(Y_{ij}, Y_{ik})
=
{\rm cov}(u_{i}, u_{i})
= {\rm var}(u_{i}) = \sigma^{2}_{u}
$$