This question arises from the one asked here about a bound on moment generating functions (MGFs).
Suppose $X$ is a bounded zero-mean random variable taking on values in $[-\sigma, \sigma]$ and let $G(t) = E[e^{tX}]$ be its MGF. From a bound used in a proof of Hoeffding's Inequality, we have that $$G(t) = E[e^{tX}] \leq e^{\sigma^2t^2/2}$$ where the right side is recognizable as the MGF of a zero-mean normal random variable with standard deviation $\sigma$. Now, the standard deviation of $X$ can be no larger than $\sigma$, with the maximum value occurring when $X$ is a discrete random variable such that $P\{X = \sigma\} = P\{X = -\sigma\} = \frac{1}{2}$. So, the bound referred to can be thought of as saying that the MGF of a zero-mean bounded random variable $X$ is bounded above by the MGF of a zero-mean normal random variable whose standard deviation equals the maximum possible standard deviation that $X$ can have.
My question is: is this a well-known result of independent interest that is used in places other than in the proof of Hoeffding's Inequality, and if so, is it also known to extend to random variables with nonzero means?
The result that prompts this question allows asymmetric range $[a,b]$ for $X$ with $a < 0 < b$ but does insist on $E[X] = 0$. The bound is $$G(t) \leq e^{t^2(b-a)^2/8} = e^{t^2\sigma_{max}^2/2}$$ where $\sigma_{\max} = (b-a)/2$ is the maximum standard deviation possible for a random variable with values restricted to $[a,b]$, but this maximum is not attained by zero-mean random variables unless $b = -a$.