Define the states 1,2,3,4,5,6,2a,6a, where states 2a and 6a are absorbing, and all other states are non-absorbing. State 1 can transition equally likely to 1,2a,3,4,5,6. States 2,3,4,5 can transition equally likely to states 1,2,3,4,5,6. State 6 can transition equally likely to 1,2,3,4,5,6a. 2a only transitions to 2a and 6a only transitions to 6a. Edit (next two sentences added for further explanation): If state 2a is reached, "1,2" wins, and the game is over, with the chain forever staying in that state. If state 6a is reached, "6,6" wins, and the game is over, with the chain forever staying in that state.
So the one-step transition matrix, with states ordered 1,2,3,4,5,6,2a,6a, is
$P =$
0.1667 0 0.1667 0.1667 0.1667 0.1667 0.1667 0
0.1667 0.1667 0.1667 0.1667 0.1667 0.1667 0 0
0.1667 0.1667 0.1667 0.1667 0.1667 0.1667 0 0
0.1667 0.1667 0.1667 0.1667 0.1667 0.1667 0 0
0.1667 0.1667 0.1667 0.1667 0.1667 0.1667 0 0
0.1667 0.1667 0.1667 0.1667 0.1667 0 0 0.1667
0 0 0 0 0 0 1.0000 0
0 0 0 0 0 0 0 1.0000
The 0.1667 entries are actually 1/6, and evaluated to full double precision accuracy in my calculations below.
The initial state distribution (after one roll) can be taken as initial state s = [1/6 1/6 1/6 1/6 1/6 1/6 1/6 0 0]. Then look at the 2a and 6a entries of $s P^n$ for n large. Using n = 1000 is more than sufficient to get all the probability to 16 significant digits into the absorbing states, with the resulting $s P^{1000} = $ zeros for states 1,2,3,4,5,6, and 0.538461538461539 for state 2a, and 0.461538461538462 for state 6a. So the probability of getting consecutive 1,2 without previously getting consecutive 6,6 is 0.538461538461539.
You might intuitively think the answer should be 0.5, but that is wrong. It is indeed a 50 50 proposition between getting to 2a vs. 6a on the 1st transition. But starting by the 2nd transition, things start moving in favor of 2a. That is because if the chain is in state 1 and fails to directly transition to 2a, it can still get to 2a in two steps (by going to 1 then 2a). But if it fails to go directly from 6 to 6a, it requires at least 3 steps to get to 6a, because it must first go to one of states 1 to 5, and then only can make it to 6a in 2 more steps after that (6 then 6a).
Here are, in order, $P^2$, $P^3$, $P^4$, which shows 2a gaining an increasing advantage over 6a.
0.1389 0.1111 0.1389 0.1389 0.1389 0.1111 0.1944 0.0278
0.1667 0.1389 0.1667 0.1667 0.1667 0.1389 0.0278 0.0278
0.1667 0.1389 0.1667 0.1667 0.1667 0.1389 0.0278 0.0278
0.1667 0.1389 0.1667 0.1667 0.1667 0.1389 0.0278 0.0278
0.1667 0.1389 0.1667 0.1667 0.1667 0.1389 0.0278 0.0278
0.1389 0.1111 0.1389 0.1389 0.1389 0.1389 0.0278 0.1667
0 0 0 0 0 0 1.0000 0
0 0 0 0 0 0 0 1.0000
0.1296 0.1065 0.1296 0.1296 0.1296 0.1111 0.2176 0.0463
0.1574 0.1296 0.1574 0.1574 0.1574 0.1343 0.0556 0.0509
0.1574 0.1296 0.1574 0.1574 0.1574 0.1343 0.0556 0.0509
0.1574 0.1296 0.1574 0.1574 0.1574 0.1343 0.0556 0.0509
0.1574 0.1296 0.1574 0.1574 0.1574 0.1343 0.0556 0.0509
0.1343 0.1111 0.1343 0.1343 0.1343 0.1111 0.0509 0.1898
0 0 0 0 0 0 1.0000 0
0 0 0 0 0 0 0 1.0000
0.1227 0.1011 0.1227 0.1227 0.1227 0.1042 0.2392 0.0648
0.1489 0.1227 0.1489 0.1489 0.1489 0.1265 0.0818 0.0733
0.1489 0.1227 0.1489 0.1489 0.1489 0.1265 0.0818 0.0733
0.1489 0.1227 0.1489 0.1489 0.1489 0.1265 0.0818 0.0733
0.1489 0.1227 0.1489 0.1489 0.1489 0.1265 0.0818 0.0733
0.1265 0.1042 0.1265 0.1265 0.1265 0.1080 0.0733 0.2083
0 0 0 0 0 0 1.0000 0
0 0 0 0 0 0 0 1.0000
This can be seen in terms of bottom line for 2a vs. 6a via the progression of $s P^n$, where it is shown in order below for n = 1,2,3,4.
0.1667 0.1389 0.1667 0.1667 0.1667 0.1389 0.0278 0.0278
0.1574 0.1296 0.1574 0.1574 0.1574 0.1343 0.0556 0.0509
0.1489 0.1227 0.1489 0.1489 0.1489 0.1265 0.0818 0.0733
0.1408 0.1160 0.1408 0.1408 0.1408 0.1197 0.1066 0.0944
Note that the number of states could be reduced by 2 by collapsing states 3,4,5 into a single state, with appropriate changes to P and initial state vector s.
Edit: In fact, the number of states can be reduced by 3, to a total of 5, by collapsing states 2 through 5 into a single state which I'll call "c". So the states are, in order, 1,c,6,2a,6a. The corresponding one state transition matrix is
0.1667 0.5000 0.1667 0.1667 0
0.1667 0.6667 0.1667 0 0
0.1667 0.6667 0 0 0.1667
0 0 0 1.0000 0
0 0 0 0 1.0000
with initial state = [1/6 2/3 1/6 0 0].
And, ta dah, for any number of steps, the absorbing probabilities for 2a and 6a match exactly to the previous formulation, as of course they should, so I do not show the results again.