They are both symmetric and more or less bell shaped, but the symmetric beta (whether at 4,4 or at any other specific value) is not actually Gaussian. You can tell this even without looking at the density -- beta distributions are on (0,1) while all Gaussian distributions are on $(-\infty,\infty)$
Let's look a bit more closely at the comparison. We'll standardize the beta(4,4) so that it has mean 0 and standard deviation 1 (a standardized beta) and look at how the density compares to a standard Gaussian:
The standardized beta(4,4) is restricted to lie between -3 and 3 (the standard Gaussian can take any value); it is also less peaked than the Gaussian and has rounder "shoulders" around 1 or so standard deviations either side of the mean. Its kurtosis is 27/11 ($\approx$2.45, vs 3 for the Gaussian).
Symmetric beta distributions with larger parameter values are closer to Gaussian.
In the limit as the parameter approaches infinity, a standardized symmetric beta approaches a standard normal distribution (example proof here).
So no specific case of the symmetric beta is Gaussian, but the limiting case of a suitably standardized beta is Gaussian. We can see this approach more easily by looking at the cdf of the beta, transformed by the quantile function of the Gaussian. On this scale the Gaussian would lie on the $y=x$ line, while the symmetric beta family would approach the $y=x$ line as the parameter got larger and larger.
In the plot below we look at the deviations from the $y=x$ line to more clearly see the approach of the beta($\alpha$,$\alpha$) to the Gaussian as $\alpha$ increases.