In this interpretation, the triangle is a right triangle of side lengths $X$ and $Y$ distributed binormally with expectations $\mu_x$ and $\mu_y$, standard deviations $\sigma_x$ and $\sigma_y$, and correlation $\rho$. We seek the distribution of $\arctan(Y/X)$. To this end, standardize $X$ and $Y$ so that
$$X = \sigma_x \xi + \mu_x$$ and $$Y = \sigma_y \eta + \mu_y$$
with $\xi$ and $\eta$ standard normal variates with correlation $\rho$. Let $\theta$ be an angle and for convenience write $q = \tan(\theta)$. Then
$$\mathbb{P}[\arctan(Y/X) \le \theta] = \mathbb{P}[Y \le q X]$$
$$=\mathbb{P}[\sigma_y \eta + \mu_y \le q \left( \sigma_x \xi + \mu_x \right)$$
$$=\mathbb{P}[\sigma_y \eta - q \sigma_x \xi \le q \mu_x - \mu_y]$$
The left hand side, being a linear combination of Normals, is normal, with mean $\mu_y \sigma_y - q \mu_x \sigma_x$ and variance $\sigma_y^2 + q^2 \sigma_x^2 - 2 q \rho \sigma_x \sigma_y$.
Differentiating the Normal cdf of these parameters with respect to $\theta$ yields the pdf of the angle. The expression is fairly grisly, but a key part of it is the exponential
$$\exp \left(-\frac{\left(\mu _y \left(\sigma _y+1\right)-\mu _x \left(\sigma _x+1\right) \tan (\theta )\right){}^2}{2 \left(-2 \rho \sigma _x \sigma _y \tan (\theta )+\sigma _x^2+\sigma _y^2+\tan ^2(\theta )\right)}\right),$$
showing right away that the angle is not normally distributed. However, as your simulations show and intuition suggests, it should be approximately normal provided the variations of the side lengths are small compared to the lengths themselves. In this case a Saddlepoint approximation ought to yield good results for specific values of $\mu_x$, $\mu_y$, $\sigma_x$, $\sigma_y$, and $\rho$, even though a closed-form general solution is not available. The approximate standard deviation will drop right out upon finding the second derivative (with respect to $\theta$) of the logarithm of the pdf (as shown in equations (2.6) and (3.1) of the reference). I recommend a computer algebra system (like MatLab or Mathematica) for carrying this out!