The method of moments estimator for AR processes can be had with the Yule-Walker equations. But how is it derived?
The equation for AR(1):
$$Y_t =aY_{t-1}+\epsilon_t$$
Where $\epsilon $ ~ $N(0,\sigma^2 )$.
So the moment conditions are $E(\epsilon)=0, E(\epsilon^2)=\sigma^2$
But the "standard" solution can't be used as $E(\epsilon)=E(Y_t-aY_{t-1})=0$ is true for any $a$.