Please correct me if I am wrong.
The general form of $k$-parameter exponential family is
$$f(x;\boldsymbol{\theta}) = a(\boldsymbol{\theta})g(x) \exp\{\sum_{i=1}^{k}b(\boldsymbol{\theta}) R_i(x)\}$$
Let $X_1, \ldots, X_n \sim \dfrac{1}{\sigma} \exp\{ -(x-\mu)/\sigma \} I(x>\mu); \mu \in R, \sigma \in R^+$ [the common pdf of negative exponential distribution]. Here, $I$ is an indicator function.
The joint distribution is
$$\dfrac{1}{\sigma^n} \exp\{ -\sum_{i=1}^{n}(x_i-\mu)/\sigma \} I(x_{n:1}>\mu)$$
which cannot be absorbed in the general expression of the exponential family mentioned above due to the part $I(x_{n:1}>\mu)$.
Thus the negative exponential distribution does not belong to the exponential family.
Please correct me if I am wrong.