Recall the construction of most powerful test using the fundamental Neyman-Pearson lemma.
Consider the problem of testing a simple null against a simple alternative, namely $$H_0:X\sim f_0\quad\text{ vs }\quad H_1:X\sim f_1\,(\ne f_0)$$
, where $X$ is a random variable/vector, $f_0$ (or $f_{H_0}$) is the null distribution which is completely specified, and $f_1$ (or $f_{H_1}$) is the alternative distribution which is also completely specified.
Then any test $\varphi$ of the form
$$\varphi(x)=\begin{cases}1&,\text{ if }f_1(x)>kf_0(x)\\ \gamma&,\text{ if }f_1(x)=kf_0(x)\\0&,\text{ if }f_1(x)<kf_0(x)\end{cases}$$
where $\gamma\in(0,1)$ and $k>0$ are such that $\varphi$ is of size $\alpha$, is a most powerful size $\alpha$ test for testing $H_0$ against $H_1$.
Since you are familiar with hypothesis testing of parameters using N-P lemma, the above would not come as much of a surprise. After all, if your distribution $f$ was indexed by the parameter $\theta$ you would do the same thing for testing, say, $H_0:\theta=\theta_0$ vs $H_1:\theta=\theta_1\,(\ne\theta_0)$. In that case, $f_0$ becomes $f_{\theta_0}$ and $f_1$ becomes $f_{\theta_1}$.
To get you started, let $f$ be the pmf of $X$.
Since both the null and alternative distributions are discrete, a most powerful level $\alpha=0.25$ test for testing $H_0$ against $H_1$ is simply of the form
$$\varphi(x)=\begin{cases}1&,\text{ if }x\in E\\0&,\text{ otherwise }\end{cases}$$
, where $$E_{H_0}\varphi(X)\le 0.25$$
To choose the set of points in $E$, compute the likelihood ratio $\lambda(x)=\frac{f_{H_1}(x)}{f_{H_0}(x)}$ for each $x$, and write the different values of $\lambda(x)$ in decreasing order (because we reject $H_0$ for large values of $\lambda(x)$).
For this question, the order looks something like $$\lambda(0)=\lambda(12)>\lambda(1)=\lambda(11)>\ldots\tag{*}$$
The critical region $E$ would consist of sample points taken according to the preference rule $(*)$. So here $0,12$ would be the first values to enter into $E$, and so on until $E_{H_0}\varphi(X)$ exceeds $0.25$.
[The test $\varphi$ might not be an exact size $\alpha$ test, in which case you would have to use randomisation.]