Okay, so this one is less about illustrating a basic concept, but it is very interesting both visually and in terms of applications. I think showing people what they can ultimately accomplish with what they are learning is a great form of motivation, so you can pitch it as an example of developing and applying statistical models, which depends on all the more fundamental statistical concepts they are learning. With that, I present to you...
Species Distribution Modelling
It's actually a very broad topic with a lot of nuance in terms of types of data, data collection, model setup, assumptions, applications, interpretations, etc. But very simply put, you take sample information about where a species occurs, then use those locations to sample potentially relevant environmental variables (e.g., climate data, soil data, habitat data, elevation, light pollution, noise pollution, etc), develop a model using the data (e.g., GLM, point process model, etc), then use that model to predict across a landscape using your environmental variables. Depending on how the model was setup, what's predicted might be potential suitable habitat, likely areas of occurrence, species distribution, etc. You can also change the environmental variables to see how they impact these results. People have used SDMs to find previously unknown populations of a species, they've used them to discover new species, with historical climate data they've used them to predict backwards in time where a species used to occur and how it got to where it is today (even all the way back through glaciation periods), and with things like future climate predictions and habitat loss, they are used to predict how human activities will affect the species in the future. These are just a few examples, and if I have time later I'll find and link interesting papers. In the meantime here's a quick image I found illustrating the basics:
