What you are observing here is an idiosyncracy of the general Chebyshev inequality. Generally speaking, the inequality gets better as the midpoint of the interval gets closer to the mean $\mu$ and it also gets better as the length of the interval increases. However, if you hold one of the bounds constant and move the other one out to expand the interval, eventually you pass a point where the midpoint of the interval is now far from the mean, and the effect of further movement of the midpoint away from the mean outweighs the effect of expanding the length of the interval. As such, the probability bound gets worse rather than getting better.
Describing the phenomenon in greater generality: A simpler and more general way to frame this phenomenon is in terms of the standardised part-lengths of the interval, which I will denote by:
$$k_- = \frac{\mu-l}{\sigma}
\quad \quad \quad \quad \quad
k_+ = \frac{u-\mu}{\sigma}.$$
The lower probability bound given by the Chebyshev inequatity can be written as:
$$B(k_-, k_+) = 4 \cdot \frac{k_- k_+ - 1}{(k_- + k_+)^2},$$
and the bound is "binding" (i.e., greater than zero) if and only if the interval contains the mean $\mu$ in its interior and we also have $k_- k_+>1$. If you hold one of these arguments constant, it can easily be shown that this function is strictly quasi-concave in the other argument. In particular, holding $k_-$ constant and varying $k_+$ gives the maximiser:
$$\underset{k_+}{\text{arg max}} \ B(k_-, k_+) = \hat{k}_+ = k_- + \frac{2}{k_-}
\quad \quad \quad \quad \quad
\underset{k_+}{\text{max}} \ B(k_-, k_+) = B(\hat{k}_+) = \frac{k_-^2}{k_-^2+1}.$$
The bound function is increasing up to $k_+ = \hat{k}_+$ and then after this it decreases. As stated above, this occurs because after we get past this point, the negative effect of moving the midpoint of the interval away from the mean outweighs the positive effect of making the interval wider.
Of course, the true probability of the interval cannot be getting smaller as you move a boundary point outward to make the interval larger. Thus, you may legitimately use the probability bound at $k_+ = \hat{k}_+$ whenever you have $k_+ > \hat{k}_+$ (and it is desirable to do this, since that lower bound is larger). Indeed, this is what is done in adjust versions of the interval. In the adjusted version, we take the generalised Chebyshev interval to be given by the formula you have written, but adjusted so that it doesn't get smaller as you move outward.