I think I can help. I'll give a partial answer and if you need more then let me know.
First I'd like to simplify the notation a bit. Let $X = (x_1, \ldots, x_N)$ denote the data, which is in parallel with $Z = (z_1, \ldots, z_N)$.
Also I will suppress the known parameters in the priors for the unknowns $(\pi,Z,\mu,\Sigma)$. With these changes, the joint posterior can be expressed as proportional to the joint distribution
\begin{equation}
p(\pi,Z,\mu,\Sigma|X) \propto p(\pi,Z,\mu,\Sigma,X) .
\end{equation}
The Gibbs sampler involves cycling through the full conditional distributions:
\begin{align}
p(\pi|X,Z,\mu,\Sigma) &\propto p(\pi,Z,\mu,\Sigma,X) \\
p(Z|X,\pi,\mu,\Sigma) &\propto p(\pi,Z,\mu,\Sigma,X) \\
p(\mu|X,\pi,Z,\Sigma) &\propto p(\pi,Z,\mu,\Sigma,X) \\
p(\Sigma|X,\pi,Z,\mu) &\propto p(\pi,Z,\mu,\Sigma,X) ,
\end{align}
where each conditional distribution is proportional to the joint distribution.
Let's begin with the distribution for $\pi$. We need to collect all the factors that involve $\pi$ and ignore the rest. Therefore,
\begin{equation}
p(\pi|X,Z,\mu,\Sigma) \propto p(\pi|\alpha)\,\prod_{i=1}^N p(z_i|\pi) .
\end{equation}
That's the main idea. You can apply it to the other unknowns.
I could stop here, but I think it will help to provide some interpretation for some of these symbols. In particular,
\begin{equation}
z_i \in \{1, \ldots, K\}
\end{equation}
is a latent classification variable the indicates which mixture component $x_i$ belongs to. Therefore,
\begin{equation}
p(x_i|z_i,\mu,\Sigma) = \textsf{N}(x_i|\mu_{z_i}, \Sigma_{z_i}) .
\end{equation}
In addition,
\begin{equation}
p(z_i|\pi) = \textsf{Categorical}(z_i|\pi) = \prod_{k=1}^K \pi_k^{1(z_i=k)}
\end{equation}
where
\begin{equation}
1(z_i=k) = \begin{cases}
1 & z_i = k \\
0 & \text{otherwise}
\end{cases} .
\end{equation}
Just to be clear, $p(z_i = k|\pi) = \pi_k$. So $\pi$ is a vector of $K$ probabilities that sum to one and (very likely, but not necessarily)
\begin{equation}
p(\pi|\alpha) = \textsf{Dirichlet}(\pi|\alpha) \propto \prod_{k=1}^K \pi_k^{\alpha_k-1} .
\end{equation}
You now have the prior and the conditional likelihood for $\pi$, which enough to figure out what the conditional posterior for $\pi$ is. So I will stop here.