This answer is essentially similar to @Thomas Lumley's, but hopefully to add more clarity by explicitly justifying some key steps.
Let $X_n = (X_{n, 1}, \ldots, X_{n, n}) \sim N_n(0, I_{(n)})$ (i.e., $X_{n, 1}, \ldots, X_{n, n} \text{ i.i.d.} \sim N(0, 1)$), then it follows by a property of spherical distribution (see, e.g., Theorem 1.5.6 in Aspects of Multivariate Statistical Theory by Robb J. Muirhead) that $X_n/\|X_n\| \sim \text{Uniform}(S_{n - 1})$, hence
\begin{align}
\sqrt{n}(U_{n, 1}, U_{n, 2}) \overset{d}{=}
\frac{\sqrt{n}}{\|X_n\|}(X_{n, 1}, X_{n, 2})
= \frac{1}{\sqrt{\frac{X_{n, 1}^2 + \cdots + X_{n, n}^2}{n}}}(X_{n, 1}, X_{n, 2}).
\tag{1}
\end{align}
By the weak law of large numbers, $\frac{X_{n, 1}^2 + \cdots + X_{n, n}^2}{n}$ converges to $E[Z^2] = 1$ in probability, where $Z \sim N(0, 1)$, whence
$\frac{1}{\sqrt{\frac{X_{n, 1}^2 + \cdots + X_{n, n}^2}{n}}}$ converges to $1$ in probability by the continuous mapping theorem. On the other hand, $(X_{n, 1}, X_{n, 2}) \sim N_2(0, I_{(2)})$ for all $n$. It thus follows by Slutsky's theorem that
\begin{align}
\frac{1}{\sqrt{\frac{X_{n, 1}^2 + \cdots + X_{n, n}^2}{n}}}(X_{n, 1}, X_{n, 2})
\to_d N_2(0, I_{(2)}). \tag{2}
\end{align}
Combining $(1)$ and $(2)$ gives $\sqrt{n}(U_{n, 1}, U_{n, 2}) \to_d N_2(0, I_{(2)})$.