The main effect for a factor may be significant at the 5% level, but the method of ad hoc testing (to avoid
'false discovery' in multiple analyses of the same data) may use a somewhat different criterion for judging differences than does the main test. In relatively rare cases, that can lead to your situation
where none of the ad hoc comparisons between any two levels of a 'significant' factor turns out to be judged significant.
IMHO, at the very least, you ought to be able to claim that the largest difference in sample means among your five levels is significant at 5%, which is a bit higher than the significance level of the effect. Is that the comparison of level 2 vs 4? Even the Dunn 'adjusted P-value' for that
comparison is significant at the 6% level. (There is nothing
'sacred' about the 5% level.)
By looking at all ${5 \choose 2} = 10$ ad hoc
comparisons among levels of this factor you may be paying a penalty with adjusted P-values larger than than necessary to avoid
false discovery.
By contrast, if you were to break the rules, doing ad hoc
comparisons for an effect that is not quite significant at the 5% level, you might occasionally find comparison among levels that
is "significant" at an adjusted significance level of 5%.
Again, that might be because main and ad hoc use slightly different criteria. Fortunately,
that discrepancy is not often noticed because most people know
not to do comparisons among levels unless the main effect is
found to be significant.
Furthermore, there is no guarantee that you will be able definitively
to rank the levels of a factor. For example, if you have five
levels of a factor, you might establish that smallest level 4 and largest level 5 are significantly different at the 5% level, but not be able to tell whether intermediate levels 1, 2, and 3 differ from 4 or from 5 or from one and other. Happily, the differences that cannot be resolved may often be too small to be of practical importance.
In general,
one can decrease the possibility of failing to distinguish important differences by doing a power and sample size analysis at the start
of the study to make sure that there are enough replications per level to resolve differences large enough to be of practical interest.
PMCMRplus
package has Dunn test, Conover test, and Nemenyi test for post-hoc analysis after Kruskal-Wallis. It also has post-hoc tests for Friedman and Quade and other rank-based tests. $\endgroup$