You are correct that you can express $Z$ either of the ways that you wrote; that’s what it means to be “equal”. However, you have a misunderstanding about the central limit theorem, which explicitly concerns $Z$, not $\bar X$.
People often like thinking of the sample mean converging so that the following holds asymptotically, as it is an algebraic rearrangement of the central limit theorem.
$$
\bar X_n \sim N(\mu, \sigma^2/n)
$$
Such a notion is problematic, as it makes the convergence target a moving target, since $n$, therefore the variance, changes as the sample size increases. Further, if we have a distribution with bounded support, you are proposing that its sample mean could be off of the support, such as $\bar X=-1$ for an exponential distribution that does not give negative values. (A normal distribution has support on the entire real line.)
Further, the sum does not have to do anything close to converge. Consider $X_1,\dots,X_n\overset{iid}{\sim} U(1,2)$. That uniform distribution meets the assumptions of the classical central limit theorem. However, a sum of those values is going to diverge off to infinity, something like $1+1.1+1.7+1.2+\dots$ At least dividing by the sample size allows the mean to be controlled and kept from exploding off to infinity.