Based on the output you have shared, your model seems to be ARCH(1) with zero mean:
\begin{aligned}
x_t &= \mu_t + u_t, \\
\mu_t &= 0, \\
u_t &= \sigma_t \varepsilon_t, \\
\sigma_t^2 &= \omega + \alpha_1 u_{t-1}^2, \\
\varepsilon_t &\sim i.i.D(0,1,\eta,\lambda)
\end{aligned}
where $D$ is standardized skewed Student-$t$ distribution with zero mean and unit variance.
Autocovariance of $\{x_t\}$ must be zero at all lags aside from zero, since
\begin{aligned}
\text{Cov}(x_t,x_{t-h}) &= \text{Cov}(u_t,u_{t-h}) \\
&= \mathbb{E}(u_t u_{t-h})-\mathbb{E}(u_t)\mathbb{E}(u_{t-h}) \\
&= \mathbb{E}(u_t u_{t-h})-0\cdot 0 \\
&= \mathbb{E}(\sigma_t\varepsilon_t \sigma_{t-h}\varepsilon_{t-h}) \\
&\stackrel{*}{=} \mathbb{E}(\mathbb{E}(\sigma_t\varepsilon_t \sigma_{t-h}\varepsilon_{t-h}\mid I_{t-1})) \\
&\stackrel{**}{=} \mathbb{E}(\sigma_t\sigma_{t-h}\varepsilon_{t-h}\mathbb{E}(\varepsilon_t \mid I_{t-1})) \\
&= \mathbb{E}(\sigma_t\sigma_{t-h}\varepsilon_{t-h}\cdot 0) \\
&= 0.
\end{aligned}
*By the law of iterated expectation.
**Note that $\sigma_t$ is known as of time $t-1$, so we are able to move it outside of $\mathbb{E}(\cdot \mid I_{t-1})$.
There may be a slight problem with $\hat\alpha_1=1.000$, though, implying that the conditional variance is an integrated process. However, I guess the non-rounded value is just under $1.000$, as this might be forced by the software that prevents integrated conditional variances.