Below, I briefly sketch out one "back of the envelope" calculation, which is in no way optimal, but does at least show that the probability converges to one exponentially fast. Before getting into the (gory) details, we give the answer.
$$
\Pr(\text{at least one actor chooses a unique outcome}) \geq 1 - (e/4)^{n/2} .
$$
As mentioned before, comparing this result to the above for small $n$ shows that the result is not super sharp. But, it does provide a guarantee for all $n$ and shows that as $n$ grows, the probability goes to 1 at least exponentially fast. (The actual rate is probability more like $e^{b n \log n + o(n)}$).
The idea is to turn the problem into an occupancy or coupon-collecting problem. If you want a more precise answer, you can refer to the (extensive) literature on these subjects, but to prove a faster rate takes messier analysis.
Let $U_n$ be the proportion of actors that choose a unique outcome (when we have $n$ total actors), which we use below. (Technically, the analysis below is for even $n$, but that's a minor point. The same result holds for odd $n$; just replace $n/2$ by $(n-1)/2$ and $3n/2$ by $(3n+1)/2$ in the relevant places.)
Restating the problem in terms of balls and bins. We have $n$ balls and $2n$ bins. The "balls" are the "actors" and the "bins" are the possible outcomes. We want to know the probability that at least one bin has only a single ball in it. The probability that any particular bin has only one ball is $\left(1 - \frac{1}{2n}\right)^n$. So, the expected proportion of balls in a bin by themselves (i.e., actors that choose a unique outcome) is
$$
\mathbb{E}(U_n) = \left(1 - \frac{1}{2n}\right)^n \to e^{-1/2} \approx 60.65\%
$$
This gives us pretty good hope that the probability of at least one ball being in a bin by itself is (very) high.
To get a bound on this probability, note that if each of the occupied bins has at least two balls in it, then at most $n/2$ bins can be occupied. So
$$
\Pr(\text{no bin has exactly 1 ball}) \leq \Pr(\text{no more than n/2 bins are occupied})
$$
Now, if no more than $n/2$ bins are occupied, then there must be some subset of $3n/2$ bins that are all empty. There are ${2n \choose 3n/2} = {2n \choose n/2}$ such subsets, and so by the union bound, we get
$$
\Pr(\text{some subset of 3n/2 bins is empty}) \leq {2n \choose n/2} \left(1 - \frac{3n/2}{2n}\right)^{n} = {2n \choose n/2} 4^{-n}
$$
To finish up, we use the elementary inequality
$$
{2n \choose n/2} \leq \left(\frac{2n e}{n/2}\right)^{n/2} = (4e)^{n/2} .
$$
Putting it all together, we get
$$
\Pr(\text{no bin has exactly 1 ball}) \leq (4 e)^{n/2} 4^{-n} = (e/4)^{n/2} .
$$
Hence,
$$
\Pr(\text{at least one actor chooses a unique outcome}) \geq 1 - (e/4)^{n/2} .
$$