Singular values of the data matrix and eigenvalues of the covariance matrix I am having some problem in computing SVD and PCA in Matlab.
I do not know if I am doing theoretical mistakes or programming mistakes.
Starting with a data matrix $X$, PCA computes the eigenvalues $\lambda_i$ of the covariance matrix $X^TX/(n-1)$.
On the other side SVD of $X$ is given by  $X=U\Sigma V^\top$, and so $$X^T X=V \Sigma^T U^T U\Sigma V^T=V \Sigma^2 V^T,$$ where $\Sigma$ is diagonal matrix of singular values with elements $\sigma_i$.
So we have that $$\lambda_i=\sigma_i^2 /(n-1).$$
Now I try a Matlab example:
    load hald;
    [u s v] = svd(ingredients);
    sigma = cov(ingredients);
    [a,b] = eig(sigma);
    disp('sigma')
    disp(diag(s)')
    disp('lambda')
    disp(diag(b)')

and here is the output: 
sigma
  211.3369   77.2356   28.4597   10.2667

lambda
    0.2372   12.4054   67.4964  517.7969

The obtained values do not respect the original equation. Where is the mistake?
 A: Aside stating the obvious: eig gives the results in ascending order while svd in descending one; the svd eigenvalues (and eigenvectors obviously) are dissimilar to those of eig decomposition because your matrix ingredients is not symmetric to start with.  To paraphrase wikipedia a bit: "When the $X$ is  a normal and/or a positive semi-definite matrix, the decomposition $\ {X} =  {U} {D} {U}^*$ is also a singular value decomposition", not otherwise. ($U$ being the eigenvectors of $XX^\mathbf{T}$)
So example if you did something like: 
rng(0,'twister')        %just set the seed.
Q = random('normal', 0,1,5);
X =  Q' * Q;            %so X is PSD 
[U S V]=    svd(X);
[A,B]=      eig(X);

max( abs(diag(S)- fliplr(diag(B)')' ))
% ans =  7.1054e-15     % AKA equal to numerical precision.

you would find that svd and eig do give you back the same results. While before exactly because matrix ingredients was not at least PSD (or even square for that matter), well.. you didn't get the same results. :) 
Just to state it in another way: $X= U\Sigma V^*$ practically translates into: $X = \sum_1^r u_i s_i v_i^T$ ($r$ being the rank of $X$). Which itself means that you are (pretty awesomely) allowed to write $X v_i = \sigma_i u_i$. Clear to get back to the eigen-decomposition $X u_i = \lambda_i u_i$ you need first all $u_i$ == $v_i$. Something that non-normal matrices do not guarantee. As final note: The small numerical differences are due to eig and svd having different algorithms working in the background; a variant of the QR algorithm of svd and a (usually) generalized Schur decomposition for eig.
Specific to your problem what you want is something akin to:
load hald;
[u s v]=svd(ingredients);
sigma=(ingredients' * ingredients); 
lambda =eig(sigma);     
max( abs(diag(s)- fliplr(sqrt(lambda)')' ))
% ans = 5.6843e-14

As you see this is nothing to do with centring you data to have mean $0$ at this point; the matrix ingredients is not centered. 
Now if you use the covariance matrix (and not a simple inner product matrix as I did) you will have to centre your data. Let's say that ingredients2 is your zero-meaned sample.
ingredients2 = ingredients - repmat(mean(ingredients), 13,1);

Then indeed you need this normalization by $1/(n-1)$
[u s v] =svd(ingredients2 );        
sigma = cov(ingredients); % You don't care about centring here
lambda =eig(sigma);   

max( abs( diag(s)- fliplr(sqrt(lambda *12)')')) % n = 13 so multiply by n-1
% ans = 4.7962e-14

So yeah, it the centring now. I was a bit misleading originally because I worked with the notion of PSD matrices rather than covariance matrices. The answer before the editing was fine. It addressed exactly why your eigen-decomposition did not fit your singular value decomposition. With the editting I show why your singular value decomposition did not fit the eigen-decomposition. Clearly one can view the same problem in two different ways. :D
