The meaning of $P$ is monotone relative to set containment is this:
If $A \subseteq B$ then $P(A)\leq P(B)$.
Now here for every $\omega\in\Omega$, we have
$$\begin{align*}
A &= \left\{\omega : \left| (X_n(\omega) + Y_n(\omega)) - ( X(\omega) + Y(\omega) ) \right| \geq \epsilon \right\}, \text{ and}\\
B &= \{ \omega : \left| X_n(\omega) - X(\omega) \right| + \left| Y_n(\omega) - Y(\omega) \right| \geq \epsilon \}.
\end{align*}$$
From your first inequality and for every $\omega\in\Omega$ and $\varepsilon >0$, we have
$$\left\{ \left| (X_n(\omega) + Y_n(\omega) - (X(\omega) + Y(\omega)) \right| \geq \varepsilon \right\} \subseteq \left\{ \left|X_n(\omega) - X(\omega)\right| + \left|Y_n(\omega) - Y(\omega)\right| \geq \varepsilon \right\}.$$
So from the statement above
$$P\left( \left| (X_n(\omega) + Y_n(\omega) - (X(\omega) + Y(\omega)) \right| \geq \varepsilon \right) \leq P\left( \left|X_n(\omega) - X(\omega)\right| + \left|Y_n(\omega) - Y(\omega)\right| \geq \varepsilon \right).$$
To show the last inequality, first we prove that for every for every $\omega\in\Omega$ and $\varepsilon >0$ we have
$$\begin{multline*}
\{\omega : \left|X_n(\omega) - X(\omega)\right| + \left|Y_n(\omega) - Y(\omega)\right| \geq \varepsilon \}\\
\subseteq \{\omega : \left|X_n(\omega) - X(\omega) \right| \geq \varepsilon/2\} \cup \{\omega : \left|Y_n(\omega) - Y(\omega) \right| \geq \varepsilon/2\}.
\end{multline*}$$
This can be simply shown by contradiction, i.e. if
$$\{ \omega : \left|X_n(\omega) - X(\omega) \right| < \varepsilon/2 \} \text{ and } \{\omega : \left|Y_n(\omega) - Y(\omega) \right| < \varepsilon/2 \}$$
then we can sum them up to get $\{ \omega : \left|X_n(\omega) - X(\omega)\right| + \left|Y_n(\omega) - Y(\omega)\right| < \varepsilon \}$, which is a contradiction.
Hence,
$$\begin{align*}
P\bigl( \{ \omega : &\left| X_n(\omega)-X(\omega) \right| + \left| Y_n(\omega) - Y(\omega) \right|\geq \varepsilon \} \bigr)\\
&\leq P\left( \{\omega : \left| X_n(\omega) - X(\omega) \right| \geq \varepsilon/2\} \cup \{\omega : \left| Y_n(\omega) - Y(\omega) \right| \geq \varepsilon/2 \} \right)\\
&\leq P\left( \{\omega : \left| X_n(\omega) - X(\omega) \right| \geq \varepsilon/2\}\right) + P\left( \{\omega : \left| Y_n(\omega) - Y(\omega) \right| \geq \varepsilon/2 \} \right),
\end{align*}$$
where the last inequality comes from $P(C \cup D) \leq P(C) + P(D)$. Cheers!