The first part of the question is answered in comments to the question: plenty of "brand-name" distributions are multimodal, such as any Beta$(a,b)$ distribution with $a\lt 1$ and $b\lt 1$. Let's turn, then, to the second part of the question.
All discrete distributions are clearly mixtures (of atoms, which are unimodal).
I will show that most continuous distributions are also mixtures of unimodal distributions. The intuition behind this is simple: we can "sand off" bumps from a bumpy graph of a PDF, one by one, until the graph is horizontal. The bumps become the mixture components, each of which is obviously unimodal.
Consequently, except perhaps for some unusual distributions whose PDFs are highly discontinuous, the answer to the question is "none": all multimodal distributions that are absolutely continuous, discrete, or a combination of those two are mixtures of unimodal distributions.
Consider continuous distributions $F$ whose PDFs $f$ are continuous (these are the "absolutely continuous" distributions). (Continuity is not much of a limitation; it can be further relaxed by more careful analysis, assuming merely that the points of discontinuity are discrete.)
To cope with "plateaus" of constant values that might occur, define a "mode" to be an interval $m = [x_l, x_u]$ (which might be a single point where $x_l=x_u$) such that
$f$ has a constant value on $m,$ say $y$.
$f$ is not constant on any interval that strictly contains $m$.
There exists a positive number $\epsilon$ such that the maximum value of $f$ attained on $[x_l-\epsilon, x_u+\epsilon]$ equals $y$.
Let $m = [x_l, x_u]$ be any mode of $f$. Because $f$ is continuous, there are intervals $[x_l^\prime, x_u^\prime]$ containing $m$ for which $f$ is nondecreasing in $[x_l^\prime, x_l]$ (which is a proper interval, not just a point) and nonincreasing in $[x_u, x_u^\prime]$ (which is also a proper interval). Let $x_l^\prime$ be the infinimum of all such values and $x_u^\prime$ the supremum of all such values.
This construction has defined one "hump" on the graph of $f$ extending from $x_l^\prime$ to $x_u^\prime$. Let $y$ be the larger of $f(x_l^\prime)$ and $f(x_u^\prime)$. By construction, the set of points $x$ in $[x_l^\prime, x_u^\prime]$ for which $f(x)\ge y$ is a proper interval $m^\prime$ strictly containing $m$ (because it contains either the whole of $[x_l^\prime, x_l]$ or $[x_u, x_u^\prime]$).

In this illustration of a multimodal PDF, a mode $m=[0,0]$ is identified by a red dot on the horizontal axis. The horizontal extent of the red portion of the fill is the interval $m^\prime$: it is the base of the hump determined by the mode $m$. The base of that hump is at height $y\approx 0.16$. The original PDF is the sum of the red fill and the blue fill. Notice that the blue fill only has one mode near $2$; the original mode at $[0,0]$ has been removed.
Writing $|m^\prime|$ for the length of $m^\prime$, define
$$p_m = {\Pr}_F(m^\prime) - y|m^\prime|$$
and
$$f_m(x) = \frac{f(x) - y}{p_m}$$
when $x \in m^\prime$ and $f_m(x)=0$ otherwise. (This makes $f_m$ a continuous function, incidentally.) The numerator is the amount by which $f$ rises above $y$ and the denominator $p_m$ is the area between the graph of $f$ and $y$. Thus $f_m$ is non-negative and has total area $1$: it is the PDF of a probability distribution. By construction it has a unique mode $m$.
Also by construction, the function
$$f_m^\prime(x) = \frac{f(x) - p_mf_m(x)}{1 - p_m}$$
is a PDF provided $p_m\lt 1$. (Obviously if $p_m=1$ there is nothing left of $f,$ which must have been unimodal to begin with.) Moreover, it has no modes in the interval $m^\prime$ (where it is constant, which is why the previous careful definition of a mode as an interval was necessary). Furthermore,
$$f(x) = p_m f_m(x) + (1-p_m)f_m^\prime(x)$$
is a mixture of the unimodal PDF $f_m$ and the PDF $f_m^\prime$.
Iterate this procedure with $f_m^\prime$ (which as a linear combination of continuous functions is still a continuous function, enabling us to proceed as before), producing a sequence of modes $m=m_1, m_2, \ldots$; corresponding sequences of weights $p_1=p_m, p_2=p_{m_2}, \ldots$; and PDFs $f_1=f_m, f_2=f_{m_2}, \ldots.$ The limiting result exists because (a) the interval where $f_i$ is flattened includes a proper interval that had not been flattened in the preceding $i-1$ operations and (b) the real numbers cannot be decomposed into more than a countable number of such intervals. The limit cannot have any modes and therefore is constant, which must be zero (for otherwise its integral would diverge). Consequently, $f$ has been expressed (perhaps not uniquely, because the order in which modes were selected will matter) as a mixture
$$f(x) = \sum_i p_i f_i(x)$$
of unimodal distributions, QED.