Consider the function p(1-p)$p(1-p)$ for 0<=p<=1$0\leq p\leq 1$. Using calculus you can see that at p=1/2 it$p=1/2$ the function is 1/4equal to $1/4$, which is the maximum value. If you can see that this is for the binomial related to the standard deviation of the estimate of the proportion which is sqrt(p(1-p)/n)$\sqrt{p(1-p)/n}$ then p=1/2$p=1/2$ is the maximum. When p=1$p=1$ or 0$p=0$ the standard error is 0 because you will always get all 1s or all 0s respectively. So as you get close to 0 or 1 a continuity argument says that the standard error approaches 0 as p$p$ approaches 0 or 1. In fact, it decreases monotonically as p$p$ approaches 0 or 1. For large n$n$ the estimated proportion should be close to the actual proportion.