Following mpiktas answer, things became clearer to me and I think I can know answer the question. The first statement
$F_U(U(\bar{\omega})) = F_X(z_{\bar{w}})$ for all $\bar{\omega} \in \Omega \implies z_{\bar{\omega}}=X(\bar{\omega})$
Is in fact equivalent to (and better understood as)
$F_U(U({\omega})) \sim F_X(Z(\omega)) \implies Z(\omega)=X({\omega})$, where $\sim$ means "distributed as".
Now, this turns out not to be quite true (see mpiktas comment below). What is true however is
$F_U(U({\omega})) \sim F_X(Z(\omega)) \implies Z(\omega) \sim X({\omega})$$F_U(U({\omega})) \sim F_X(Z(\omega)) \implies Z(\omega) =^d X({\omega})$, where $=^d$ means that the two random variables have the same distribution.
As noticed by mpiktas, $F_U(U({\omega})) \sim U(0,1)$ ( a proof can be found here). Hence we must have $F_X(Z(\omega)) \sim U(0,1)$. But then we must have $Z(\omega) \sim X(\omega)$$Z(\omega) =^d X(\omega)$. All that is needed for the proof of this last fact can also be found here. But in the link, the statement is reversed ($F_X(X(\omega)) \sim U(0,1)$ instead of $F_X(Z(\omega)) \sim U(0,1) \Rightarrow Z(\omega) \sim X(\omega)$$F_X(Z(\omega)) \sim U(0,1) \Rightarrow Z(\omega) =^d X(\omega)$ ) so I figured it might be helpful to reformulate it here.
- Assume $F_X(Z(\omega)) \sim U(0,1)$.
- Then $F_{F_X(Z(\omega))}(a) = a$
- Notice that \begin{align} a &= F_X(F^{-1}_X(a))\\ &= P(X\leq F^{-1}_X(a))\\ &= P(F_X(X) \leq a)\\ &= F_{ F_X(X)} (a) \end{align} where I omitted the $\omega$'s for notational convenience.
- So we have $F_{F_X(Z(\omega))}(a) = a = F_{ F_X(X(\omega))} (a)$, which in turn implies $Z(\omega) \sim X(\omega)$$Z(\omega) =^d X(\omega)$.