Question :
A die is marked on one side, and the number of times that the mark appears is recorded.
The mark appears once from 25 rolls, is the die biased?
working
$H_0 : $ The die is not biased
$H_1 : $ The die is biased
For this note that the die should follow $\sim Bin(n, p)$ as $\sim Bin(25, \frac{1}{6})$.
Testing at a $95\%$ significance level we need $P(x \leq 1)$, where $x = $ number of rolls with the mark atop. This is found from $P(0) + P(1)$ using:
\begin{aligned} P(0) = {25 \choose 0}\left( \frac{1}{6} \right)^{0}\left( 1 - \frac{1}{6} \right)^{25} \\ P(1) = {25 \choose 1}\left( \frac{1}{6} \right)^{1}\left( 1 - \frac{1}{6} \right)^{24} \\ \end{aligned}
Which gives
\begin{aligned} P(0) \approx 0.0104 \\ P(1) \approx 0.0524 \end{aligned}
Therefore the probability is $P(0) + P(1) = 0.0628 $, as we're testing at a $95\%$ level we have
$$ 0.0628 > 0.05 $$
Meaning that the probability of the observed outcome isn't less than $5\%$, and therefore we don't reject $H_0$.
edit
As stated the probability has been conducted for a one tailed test yet I've not been specific about whether I'm using two or one. So that I would change the hypothesis to read as:
$H_0$: The die is fair.
$H_1$: The die is biased such that there are less results of the marked side than there would be for a non biased die.