$q_Z$ could be anything.
To understand this situation, let us make a preliminary simplification. By working with $Y_i = X_i - q_i$ we obtain a more uniform characterization
$$\alpha = \Pr(X_i \le q_i) = \Pr(Y_i \le 0).$$
That is, each $Y_i$ has the same probability of being negative. Because
$$W = \sum_i Y_i = \sum_i X_i - \sum_i q_i = Z - \sum_i q_i,$$
the defining equation for $q_Z$ is equivalent to
$$\alpha = \Pr(Z \le q_Z) = \Pr(Z - \sum_i q_i \le q_Z - \sum_i q_i) = \Pr(W \le q_W)$$
with $q_Z = q_W + \sum_i q_i$.
What are the possible values of $q_W$? Consider the case where the $Y_i$ all have the same distribution with all probability on two values, one of them negative ($y_{-}$) and the other one positive ($y_{+}$). The possible values of the sum $W$ are limited to $ky_{-} + (n-k)y_{+}$ for $k=0, 1, \ldots, n$. Each of these occurs with probability
$${\Pr}_W(ky_{-} + (n-k)y_{+}) = \binom{n}{k}\alpha^k(1-\alpha)^{n-k}.$$
The extremes can be found by
Choosing $y_{-}$ and $y_{+}$ so that $y_{-} + (n-1)y_{+} \lt 0$; $y_{-}=-n$ and $y_{+}=1$ will accomplish this. This guarantees that $W$ will be negative except when all the $Y_i$ are positive. This chance equals $1 - (1-\alpha)^n$. It exceeds $\alpha$ when $n\gt 1$, implying the $\alpha$ quantile of $W$ must be strictly negative.
Choosing $y_{-}$ and $y_{+}$ so that $(n-1) y_{-} + y_{+} \gt 0$; $y_{-}=-1$ and $y_{+}=n$ will accomplish this. This guarantees that $W$ will be negative only when all the $Y_i$ are negative. This chance equals $\alpha^n$. It is less than $\alpha$ when $n\gt 1$, implying the $\alpha$ quantile of $W$ must be strictly positive.
This shows that the $\alpha$ quantile of $W$ could be either negative or positive, but is not zero. What could its size be? It has to equal some integral linear combination of $y_{-}$ and $y_{+}$. Making both these values integers assures all the possible values of $W$ are integral. Upon scaling $y_{\pm}$ by an arbitrary positive number $s$, we can guarantee that all integral linear combinations of $y_{-}$ and $y_{+}$ are integral multiples of $s$. Since $q_W \ne 0$, it must be at least $s$ in size. Consequently, the possible values of $q_W$ (and whence of $q_Z$) are unlimited, no matter what $n\gt 1$ may equal.
The only way to derive any information about $q_Z$ would be to make specific and strong constraints on the distributions of the $X_i$, in order to prevent and limit the kind of unbalanced distributions used to derive this negative result.