Say I have fitted a model using
proc reg data = data;
model a = b;
run;
How do I test if the coefficient of b is, say, less than 1?
This is in no way specific to SAS but if you have the coefficient estimate, $\hat{\beta}$ and the standard error, $s$, and you want to test the null hypothesis $H_{0} : \beta = \beta_{0}$ then the test statistic is
$$ T = \frac{ \hat{\beta} - \beta_{0} }{ s } $$
which has a $t$-distribution with $n-2$ degrees of freedom, denoted by $t_{n-2}$. To do a 1-sided test of "greater than" calculate the area to the right of $T$ under the $t_{n-2}$ distribution. Similarly, to do a one-sided test of "less than", calculate the area to the left. To do a two-sided test, find twice the area to the left of $-|T|$. I'm no SAS expert but I believe the areas under the $t$-distribution can be calculated using the tinv() command.
Use the TEST statement. So for your example you would have:
proc reg data = data;
model a = b;
test b=1;
run;