You can directly calculate the mean of $X^2$,suppose your exponential distribution is $f(x;\lambda)=\lambda e^{-\lambda x}$.
$E(X^2)=\int_{0}^{\infty}x^2\lambda e^{-\lambda x}dx$ by integral by parts you can get $E(X^2)=\frac{2}{\lambda^2}=2\theta^2$.
By the same method you can calculate $E(X^4)$.
You also can calculate $E(X^2)$ and $E(X^4)$ by using moment generating function if you remember:
$E(X^m)=M^{(m)}(0)$, $M$ is the mgf and $(m)$ is the order of derivative.
The mgf of the exponential distribution is $\frac{\lambda}{\lambda-t}$
The first derivative (m=1) of the mgf in term of $t$ is $\frac{\lambda}{(\lambda-t)^2}$, set $t=0$, $E(X)=\frac{1}{\lambda}=\theta$
The second derivative (m=2) of the mgf in term of $t$ is $\frac{2\lambda}{(\lambda-t)^3}$, set $t=0$, $E(X^2)=\frac{2}{\lambda^2}=2\theta^2$.
You can continue to calculate others...