The key here is the difference between "identical variables" and "identically distributed variables". For a non-statistical example, imagine a factory making a particular model of car. Even if the manufacturing and assembly process remains identical (the same distribution), there will still be variability in the cars themselves (the values). If the process is tightly controlled, this will produce a distribution with little spread; if the process is less controlled, the distribution will be more spread out. Either way, some of the cars will be a number of millimeters (or microns if the process is even more tightly controlled) wider/narrower, longer/shorter, and higher/lower and a number of grams (or milligrams) heavier/lighter than typical (the mean could be used to describe the typical value for each of these attributes). You could take other measurements for colour, fuel economy, acceleration, etc. and the same would also apply.
Compare this with a science-fiction duplicator that produces atomic-level identical cars (values). They would simply be the same car (variable).
If we get ten cars from the factory, they will have a sum of their lengths (which won't be ten identical values providing we are using sufficiently precise measurements, setting aside the idea of quanta here limiting precision so that identical values could occur), a sum of their heights (the same), etc. (You could also look at means rather than sums here). The sum of the lengths of the ten cars will not necessarily be equal to the sum of the lengths of the first car and its nine duplicates.
Another way of looking at this is that the measurements from the factory car will have non-zero standard deviations, the measurements from the duplicated cars will have no variability whatsoever.