As per the weak law of large numbers, if your sample size is large, your mean of the sample is likely to be closer to the population mean than in a smaller sample. Additionally the CLT tells us the approximate sampling distribution of the sample mean tends to a normal curve for larger and larger Ns.
But what about other population parameters, such as the variance or perhaps other measures? Do we know that sample estimates tend to the true value and that their distribution is approximately normal in larger samples?