If you specify the robust
option, you are telling Stata that you don't really believe the errors are homoskedastic. There are several implications:
The sums of squared residuals are still used to drive the estimation (you minimize them).
As every observation has its own variance, the sum of the squared errors is no longer distributed as a $\chi^2$, and the ratios of the model and residual sums of squares are no longer distributed as an $F$.
Since different observations contribute different amount of information, there isn't any way now to correct $R^2$ for the prognostic value the way $R^2_{\rm adj}$ does: one observation $\neq$ one degree of freedom.
Essentially, as the notion of variance is not quite applicable to the dependent variable (do you want to talk about the conditional variance of $Y$, i.e., the variance of the error terms, which, as we said, is not constant any more; or do you want to talk about the total variance, which, inconveniently, depends on the distribution of the explanatory variables), the whole concept of $R^2$ starts breaking down in its meaning.