\begin{align}
L(\mu,\sigma) & = \prod_{i=1}^n \left( \frac 1 \sigma e^{-(x_i-\mu)/\sigma} \right) \\[8pt]
& = \frac 1 {\sigma^n} e^{-\sum_{i=1}^n (x_i-\mu)/\sigma}.
\end{align}
As $\mu$ increases, $L(\mu,\sigma)$ increases until $\mu$ gets as big as $\min\{x_1,\ldots,x_n\}.$ Therefore the MLE of $\mu$ is $\min\{x_1,\ldots,x_n\}.$ So we have
\begin{align}
L(\min,\sigma) & = \frac 1 {\sigma^n} e^{-\sum_{i=1}^n (x_i - \min)/\sigma} \\[8pt]
\ell(\min,\sigma) = \log L(\min,\sigma) & = -n\log\sigma - \sum_{i=1}^n (x_i - \min)/\sigma. \\[8pt]
\frac\partial{\partial\sigma} \ell(\min,\sigma) & = - \frac n\sigma + \frac 1 {\sigma^2} \sum_{i=1}^n (x_i-\min) \\[8pt]
& = \frac{-n\sigma + (\text{the sum above})}{\sigma^2} \qquad \begin{cases} >0 & \text{if } 0<\sigma< \text{sum}/n, \\ =0 & \text{if } \sigma= \text{sum}/n, \\ <0 & \text{if } \sigma > \text{sum}/n. \end{cases}
\end{align}
So the MLE for $\sigma$ is $\displaystyle \frac 1 n \sum_{i=1}^n \left( x_i - \min\{x_1, \ldots, x_n \} \right).$
Then the equivariance of MLEs says that the MLE for $\mu/\sigma$ is
$$
\min\{x_1,\ldots,x_n\} \left/ \left( \frac 1 n \sum_{i=1}^n (x_i - \min\{x_1,\ldots,x_n\} \right)\right. . \tag 1
$$
Alternatively, we can let $\alpha = \dfrac\mu\sigma$ and then we have this density for each observation:
$$
f(x) = \frac 1 \sigma e^{-(x/\sigma) + \alpha} \quad \text{for } x\ge\alpha\sigma.
$$
Then find the MLE for $(\alpha,\sigma).$ The MLE for $\alpha$ will be what you see in line $(1)$ above.