Based on the comments on Ben's answer, I am going to offer up two different interpretations of this variant of Monty Hall, differing to Ruben van Bergen's.
The first one I am going to call Liar Monty and the second one Unreliable Monty. In both versions the problem proceeds as follows:
(0) There are three doors, behind one of which is a car and behind the other two are goats, distributed randomly.
(1) Contestant chooses a door at random.
(2) Monty picks a door different to the contestant's door and claims a goat is behind it.
(3) Contestant is offered to switch to the third unpicked door, and the problem is "When should the contestant switch in order to maximise the probability of finding a car behind the door?"
In Liar Monty, at step (2), if the contestant has picked a door containing a goat, then Monty picks a door containing the car with some predefined probability (i.e. there is a chance between 0 and 100% that he will lie that a goat is behind some door). Note that in this variant, Monty never picks a door containing the car (i.e. cannot lie) if the contestant chose the car in step (1).
In Unreliable Monty, there is a predefined probability that the door Monty pick's in step (2) contains a car. I take from your comment on Ben's answer that this is the scenario you are interested in, and both of my versions differ from Ruben van Bergen's. Note that Unreliable Monty is not the same as Liar Monty; we will rigorously differentiate between these two cases later. But consider this, in this scenario, Monty's door can never contain the car more than $\frac{2}{3}$ of the time, since the contestant has a probability of choosing the car $\frac{1}{3}$ of the time.
To answer the problem, we are going to have to use some equations. I am going to try and phrase my answer so that it is accessible. The two things that I hope are not too confusing are algebraic manipulation of symbols, and conditional probability. For the former, we will use symbols to denote the following:
$$\begin{split}
S &= \text{The car is behind the door the contestant can switch to.}\\
\bar{S} &= \text{The car is not behind the door the contestant can switch to.}\\
M &= \text{The car is behind the door Monty chose.}\\
\bar{M} &= \text{The car is not behind the door Monty chose.}\\
C &= \text{The car is behind the door the contestant chose in step (1).}\\
\bar{C} &= \text{The car is not behind the door the contestant chose in step (1).}
\end{split}
$$
We use $\Pr(*)$ to denote "the probability of $*$", so that, put together, something like $\Pr(\bar{M})$ means the probability that the car is not behind the door Monty chose. (I.e. wherever you see an expression involving the symbols, replace the symbols with the "English" equivalents.)
We will also require some rudimentary understanding of conditional probability, which is roughly the probability of something happening if you have knowledge of another related event. This probability will be represented here by expressions such as $\Pr(S|\bar{M})$. The vertical bar $|$ can be thought of as the expression "if you know", so that $\Pr(S|\bar{M})$ can be read as "the probability that the door the contestant can switch to has the car, if you know that the car is not behind Monty's door. In the original Monty Hall problem, $\Pr(S|\bar{M}) = \frac{2}{3}$, which is larger than $\Pr(S) = \frac{1}{3}$, which corresponds to the case when Monty has not given you any information.
I will now demonstrate that Unreliable Monty is equivalent to Liar Monty. In Liar Monty, we are given the quantity $\Pr(M|\bar{C})$, the probability that Monty will lie about his door, knowing that the contestant has not chosen the car. In Unreliable Monty, we are given the quantity $\Pr(M)$, the probability that Monty lies about his door. Using the definition of conditional probability $\Pr(M \text{ and } \bar{C}) = \Pr(\bar{C} | M) \Pr(M) = \Pr(M | \bar{C}) \Pr(\bar{C})$, and rearranging, we obtain:
$$
\begin{split}
\Pr(M) &= \frac{\Pr(M | \bar{C}) \Pr(\bar{C})}{\Pr(\bar{C} | M)}\\
\frac{3}{2} \Pr(M) &= \Pr(M | \bar{C}),
\end{split}$$
since $\Pr(\bar{C})$, the probability that the car is not behind the contestant's chosen door is $\frac{2}{3}$ and $\Pr(\bar{C} | M)$, the probability that the car is not behind the contestant's chosen door, if we know that it is behind Monty's door, is one.
Thus, we have shown the connection between Unreliable Monty (represented by LHS of the above equation) and Liar Monty (represented by the RHS). In the extreme case of Unreliable Monty, where Monty chooses a door that hides the car $\frac{2}{3}$ of the time, this is equivalent to Monty lying all the time in Liar Monty, if the contestant has picked a goat originally.
Having shown this, I will now provide enough information to answer the Liar version of the Monty Hall Problem. We want to calculate $\Pr(S)$. Using the law of total probability:
$$\begin{split}
\Pr(S) &= \Pr(S|C)\Pr(C) + \Pr(S|\bar{C} \text{ and } M)\Pr(\bar{C} \text{ and } M) + \Pr(S|\bar{C} \text{ and } \bar{M})\Pr(\bar{C} \text{ and } \bar{M})\\
&= \Pr(\bar{C} \text{ and } \bar{M})
\end{split}$$
since $\Pr(S|C) = \Pr(S|\bar{C} \text{ and } M) = 0$ and $\Pr(S|\bar{C} \text{ and } \bar{M}) = 1$ (convince yourself of this!).
Continuing:
$$\begin{split}
\Pr(S) &= \Pr(\bar{C} \text{ and } \bar{M})\\
&= \Pr(\bar{M} | \bar{C}) \Pr(\bar{C}) \\
&= \frac{2}{3} - \frac{2}{3}\Pr(M | \bar{C}))
\end{split}$$
So you see, when Monty always lies (aka $\Pr(M | \bar{C})) = 1$) then you have a zero chance of winning if you always switch, and if he never lies then the probability the car is behind the door you can switch to, $\Pr(S)$, is $\frac{2}{3}$.
From this you can work out the optimal strategies for both Liar, and Unreliable Monty.
Addendum 1
In response to comment (emphasis mine):
"I added more details in my comment to @alex - Monty is never hostile
nor devious, just FALLIBLE, as sometimes he can be wrong for whatever
reasons, and never actually opens the door. Research shows that Monty
is wrong roughly 33.3% of the time, and the car actually turns out to
be there. That is a Posterior Probability of being correct 66.6% of
the time, correct? Monty never chooses YOUR door, and you will never
choose his. Do these assumptions change anything?"
This is as I understand, the Unreliable Monty Hall Problem introduced at the start of my answer.
Therefore, if Monty's door contains the car $\frac{1}{3}$ of the time, we have the probability of winning when you switch to the last unpicked door as:
$$
\begin{split}
\Pr(S) &= \frac{2}{3} - \frac{2}{3}\Pr(M | \bar{C})\\
&= \frac{2}{3} - \frac{2}{3} \times \frac{3}{2}\Pr(M) \\
&= \frac{2}{3} - \frac{1}{3}\\
&= \frac{1}{3}
\end{split}$$
Thus, there is no difference between switching, remaining with the original door or if allowed, switching to Monty's chosen door (in line with your intuition.)