Consider the most basic example, the sample mean from an i.i.d. sample of size $n$, $\bar X_n$.
We know that as $n \rightarrow \infty$, $\bar X_n \rightarrow \mu$, where $\mu$ is the common mean, the expected value, of the random variables from which the sample is generated.
So at the limit, $\bar X$ has a degenerate distribution, which is the formal way to say that it convergences to a constant. Constant terms can be considered as degenerate random variables. We usually say "constants do not have a distribution", but since sometimes issues of existence matter (meaning that the phrase "the distribution does not exist" properly means that the statistic we examine goes to infinity as the sample size goes to infinity), the correct way to distinguish the two cases is to say "the distribution of a constant is degenerate".
And what do we do, in order to obtain a non-degenerate asymptotic distribution? We create a function of the sample mean, that does not converge to a constant, but it doesn't diverge either. In the case of the sample mean, this function is $\sqrt n(\bar X_n -\mu)$.
In analogous spirit, in Extreme Value Theory, the extreme order statistics, either diverge (if the distribution has unbounded support), or tend to a constant (if the distribution has bounded support on their side). In both cases, we don't get a limiting distribution. So we need to find a function of the extreme order statistic, which will converge to a non-constant random variable and hence, with a usable distribution. The deterministic sequences $\{a_n\}$ and $\{b_n\}$, together with the statistic, create this function. Finding these sequences is not that simple, see for example this post.
Regarding the example given by @Glen_b for the maximum order statistic from a Uniform $U(0,1)$ (a distribution with bounded support), intuitively, as the sample size increases, we will obtain at least one realization of the random variable that exactly equals its upper bound. But this means that $X_{(n)} \rightarrow \max X$, which is a constant, and so it has a degenerate distribution. So we need to find a function of $X_{(n)}$ that does not diverge, and does converge to a random variable. In the specific case, this function is indeed $Z = n(1-X_{(n)})$. To see this, use the change of variable formula to find that
$$Z =n(1-X_{(n)}) \Rightarrow X_{(n)} = 1-\frac Zn \Rightarrow \left|\frac {\partial X}{\partial Z} \right|= \frac 1n$$
and note that $Z \in [0,n]$.
Therefore
$$f_Z(z) = \left|\frac {\partial X}{\partial Z} \right| f_{X_{(n)}}(1-z/n) = \frac 1n \left (nf_X(1-z/n)[F_X(1-z/n)]^{n-1}\right)$$
But $f_X(\cdot) =1$, and $F_X(x) =x$. So
$$f_Z(z) =\left(1-\frac zn\right)^{n-1}$$
and
$$F_Z(z) = \int_{0}^z\left(1-\frac tn\right)^{n-1}dt = 1-\left(1-\frac zn\right)^{n}$$
Then
$$\lim_{n\rightarrow \infty}F_Z(z) = 1-\lim_{n\rightarrow \infty}\left(1-\frac zn\right)^{n} = 1-e^{-z}$$
which is the distribution function of a standard exponential (i.e. with mean value $1$).