You actually ask two questions here, one of which is meaningless and the other meaningful (but which may not be what you mean).
First, you ask what is the correlation between two discrete and unordered variables. This question doesn't make sense. The correlation is not defined for two discrete, multi-category variables. Then you ask
i.e. to show high probability of the two variables being the same
letter
You can show the probability simply by adding up the cases of A/A, B/B etc and dividing by the total number of cases, but if you want a statistic of agreement, you can look into Cohen's $\kappa$,
$\kappa = \frac{Pr(a)-Pr(e)}{1-Pr(e}$
where $Pr(a)$ is the probability of agreement and $Pr(e)$ is the probability of chance agreement. There are online calculators for this; it is also available in R, SAS, etc. There are also weighted versions, if some disagreements are worse than others.
But if you want to see if two discrete variables are related in a more general sense, you may want $\chi^2$.