Here's a very simple solution. It involves no integration and only the easiest algebra.
Let $X=2U-1$ and $Y=2V-1.$ These are iid uniform random variables on $[-1,1]$ and therefore are symmetric about $0:$ that is, $-X$ and $-Y$ have the same distribution, too. Thus
$$\begin{aligned}
\operatorname{Cov}(XY, X+Y) &= \operatorname{Cov}((-X)(-Y),\ (-X)+(-Y)) \\
&= \operatorname{Cov}(XY,\ -(X+Y)) \\
&= -\operatorname{Cov}(XY,\ X+Y).
\end{aligned}$$
Since $X$ and $Y$ are bounded, their covariance exists and is finite. The only number equal to its own negative is $0:$ that must be the covariance.
Now exploit the basic rules of covariance (bilinearity) to relate this result to what you want:
$$\begin{aligned}
0 &= \operatorname{Cov}(XY,\ X+Y) = \operatorname{Cov}((2U-1)(2V-1),\ (2U-1)+(2V-1)) \\
&= \operatorname{Cov}(4UV-2(U+V),\ 2U+2V)\\
&= 8\operatorname{Cov}(UV,\ U+V) - 4\operatorname{Cov}(U+V,\ U+V)
\end{aligned}$$
Because $U+V$ is not constant, it has positive covariance, whence the left hand side of the last line cannot be zero. This means $UV$ and $U+V$ have positive covariance and therefore cannot be independent, QED.
BTW, if you wish to do the integrals you can compute that the common variance of $U$ and $V$ must be $1/12$ and conclude (from the independence of $(U,V)$) that $$\operatorname{Cov}(UV, U+V)=\frac{4}{8}\operatorname{Cov}(U+V,U+V) = \frac{4}{8}\left(\frac{1}{12}+\frac{1}{12}\right)=1/12.$$
To find the distribution of $Z=XY,$ observe that it, too, must be symmetric about $0$ and the distribution of its positive part must be that of $UV.$ That distribution function is
$$\Pr(UV \le t) = \iint^{(1,1)}_{uv \le t} \mathrm{d}u\mathrm{d}v = t(1-\log(t))$$
for $0 \lt t \le 1.$ Consequently
$$\Pr(-t \le Z \le t) = t(1-\log(t)),$$
which is a useful formula for the distribution of $Z.$ In particular, its density at both $\pm t$ must be half the derivative of this expression, giving
$$f_Z(t) = -\frac{1}{2}\log|t|,\ -1 \le t \le 1; t\ne 0.$$
(The density is not defined at $0.$)
The figure is a histogram of a million draws of $XY$, over which is plotted in red a graph of $f_Z.$ They match.