The Chi-squared distribution $\chi^2(\nu)$ is the the Gamma distribution ${\cal G}(\nu/2,1/2)$. Then $\frac{1}{m}X \sim {\cal G}(m/2,m/2)$ and $\frac{1}{n}Y \sim {\cal G}(n/2,n/2)$. These are Gamma distributions with different rate parameters (the second parameter) when $m \neq n$, and there is no closed-form formula (or formula in terms of elementary functions) for the convolution (sum of two independent) of these distributions.
I don't know whether there is a known approximation but I would not be surprised this question has already been adressed here. However, depending on what you exactly want, the Welch-Satterthwaite approximation might be an answer.