The term "significance" should optimally be used referring to test results together with a level indication, such as "the data provide a significant indication against the null hypothesis at level 0.05". Using it with p-values such as "p=0.005 is more significant than p=0.04" is still correct, but somewhat harder to process for non-statisticians. Generally significance always refers to data being incompatible, according to a statistical test, with the data. Otherwise in the interest of clear communication better don't use the word "significant" referring to statistical results.
In particular, the term does not apply to confidence intervals, despite the mathematical relation between confidence levels and significance levels as explained by @Ben. A confidence interval does not regard a single null hypothesis, which is what "significance" is about.
There are no better or worse confidence/significance levels, as there is always a trade-off. The larger the confidence level, the bigger the confidence interval becomes, which means it indicates less precisely where the parameter is, but the smaller the "error probability", i.e., the probability of having the true value not captured in the interval. We want a small interval and a small error probability, so we need to decide how to balance these.
The only thing that can be said is that we want to have a large probability to not miss the true parameter, or, for a test, a small probability to reject a true H0, so confidence levels should be "large" and significance levels "small", but "small" can mean 0.05, 0.01, even 0.001 or 0.1, and values such as 0.019 should only be avoided because they smell of "the author just picked what they needed", so better use widely applied standards, but there isn't anything intrinsically wrong with them.
80% as confidence level is already quite low in my view, it means "1 in 5 cases we go wrong", which, so to say, "can happen all the time", so I wouldn't go that low or even lower, but mathematically also 80% or 65% confidence intervals are not invalid.