This Venn diagram displays a situation where the chance of mutual intersection is zero:
From $\Pr(E\cap F) = 1/3$ we deduce all this probability lies in the overlap of the $E$ and $F$ disks, but not in the mutual overlap of all three disks. That permits us to update the diagram:
Applying the same reasoning to $\Pr(F\cap G) = \Pr(E\cap G) = 1/3,$ we obtain a Venn diagram displaying all the information in the question:
The Axiom of Total Probability asserts the sum of all the probabilities (including the probability for the complement of $E\cup F\cup G,$ shown at the bottom left) is $1.$
An even more basic probability axiom asserts all probabilities must be non-negative. But since $1/3+1/3+1/3+0=1,$ all the possible probability already appears. The remaining probabilities must be zero, meaning the picture can be completed only like this:
Finally, a third axiom (the same one used in the second step of filling in the Venn diagram) asserts the probability of $E$ equals the sum of the probabilities of its four parts, because they are disjoint. Thus, beginning with the central probability and moving counterclockwise around the disk that portrays $E,$
$$\Pr(E) = 0 + 1/3 + 0 + 1/3 = 2/3.$$
One moral worth remembering:
Draw Venn diagrams in full generality so they show all possible intersections of the sets, even when you know some of the probabilities are zero.
This helps you keep track of all the information systematically. (It's also conceptually more accurate, because sets of probability zero do not have to be nonempty!)